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dc.contributor.authorHicks, Jamie
dc.contributor.authorVasko, Petra
dc.contributor.authorGoicoechea, Jose M.
dc.contributor.authorAldridge, Simon
dc.date.accessioned2020-06-24T13:18:39Z
dc.date.available2020-06-24T13:18:39Z
dc.date.issued2021
dc.identifier.citationHicks, J., Vasko, P., Goicoechea, J. M., & Aldridge, S. (2021). The Aluminyl Anion : A New Generation of Aluminium Nucleophile. <i>Angewandte Chemie</i>, <i>60</i>(4), 1702-1713. <a href="https://doi.org/10.1002/anie.202007530" target="_blank">https://doi.org/10.1002/anie.202007530</a>
dc.identifier.otherCONVID_36028313
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/70782
dc.description.abstractTrivalent aluminium compounds are well known for their reactivity as Lewis acids/electrophiles, a feature that is exploited in many pharmaceutical, industrial and laboratory-based reactions. Recently, a series of isolable aluminium(I) anions ('aluminyls') have been reported, which offer an alternative to this textbook description: these reagents behave as aluminium nucleophiles. This minireview covers the synthesis, structure and reactivity of aluminyl species reported to date, together with their associated metal complexes. The frontier orbitals of each of these species have been investigated using a common methodology to allow for a like-for-like comparison of their electronic structure and a means of rationalising (sometimes unprecedented) patterns of reactivity.en
dc.format.mimetypeapplication/pdf
dc.languageeng
dc.language.isoeng
dc.publisherWiley-VCH Verlag
dc.relation.ispartofseriesAngewandte Chemie
dc.rightsIn Copyright
dc.subject.otheralumiiniyhdisteet
dc.subject.otheraluminyl
dc.subject.otheraluminium
dc.subject.othernucleophile organometallic
dc.subject.othermain group
dc.titleThe Aluminyl Anion : A New Generation of Aluminium Nucleophile
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-202006244972
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.description.reviewstatuspeerReviewed
dc.format.pagerange1702-1713
dc.relation.issn1433-7851
dc.relation.numberinseries4
dc.relation.volume60
dc.type.versionacceptedVersion
dc.rights.copyright© 2020 WILEY
dc.rights.accesslevelopenAccessfi
dc.relation.grantnumber314794
dc.subject.ysoreaktiivisuus
dc.subject.ysoalumiini
dc.subject.ysokompleksiyhdisteet
dc.subject.ysoorganometalliyhdisteet
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p19397
jyx.subject.urihttp://www.yso.fi/onto/yso/p19563
jyx.subject.urihttp://www.yso.fi/onto/yso/p30190
jyx.subject.urihttp://www.yso.fi/onto/yso/p28123
dc.rights.urlhttp://rightsstatements.org/page/InC/1.0/?language=en
dc.relation.doi10.1002/anie.202007530
dc.relation.funderSuomen Akatemiafi
dc.relation.funderAcademy of Finlanden
jyx.fundingprogramTutkijatohtori, SAfi
jyx.fundingprogramPostdoctoral Researcher, AoFen
jyx.fundinginformationJH would like to thank the Australian Research Council and the Australian Government for funding aspects of this work (DE190100524). PV thanks the Academy of Finland (Grant No. 314794) and Prof. Heikki M. Tuononen for continued support and computational resources. JMG and SA would also like to thank the Leverhulme Trust (F/08699/E) for funding aspects of this work.


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