dc.contributor.author | Jurček, Ondřej | |
dc.contributor.author | Puttreddy, Rakesh | |
dc.contributor.author | Topić, Filip | |
dc.contributor.author | Jurček, Pia | |
dc.contributor.author | Zarabadi-Poor, Pezhman | |
dc.contributor.author | Schröder, Hendrik V. | |
dc.contributor.author | Marek, Radek | |
dc.contributor.author | Rissanen, Kari | |
dc.date.accessioned | 2020-05-04T07:40:08Z | |
dc.date.available | 2020-05-04T07:40:08Z | |
dc.date.issued | 2020 | |
dc.identifier.citation | Jurček, O., Puttreddy, R., Topić, F., Jurček, P., Zarabadi-Poor, P., Schröder, H. V., Marek, R., & Rissanen, K. (2020). Heads or Tails? Sandwich-Type Metallocomplexes of Hexakis(2,3-di-O-methyl)-α-cyclodextrin. <i>Crystal Growth and Design</i>, <i>20</i>(6), 4193-4199. <a href="https://doi.org/10.1021/acs.cgd.0c00532" target="_blank">https://doi.org/10.1021/acs.cgd.0c00532</a> | |
dc.identifier.other | CONVID_35349494 | |
dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/68804 | |
dc.description.abstract | Native and synthetically modified cyclodextrins (CDs) are useful building blocks in construction of large coordination complexes and porous materials with various applications. Sandwich-type complexes (STCs) are one of the important groups in this area. Usually, coordination of secondary hydroxyls or the “head” portal of native CD molecules to a notional multinuclear ring of metal cations leads to formation of head-to-head STCs. Our study introduces a new CD-ligand, hexakis(2,3-di-O-methyl)-α-cyclodextrin, which enables formation of intriguing head-to-head, but also novel tail-to-tail STCs. Homometallic silver-based head-to-head STCs, AgPF6-STC and AgClO4-STC, were obtained by coordination of ligand methoxy groups to six Ag+, while bulky counter-anions are located on the outside but also filling the inner space of infinite linear channels formed. In contrast, unique homometallic tail-to-tail RbF-STC was prepared by complexation of primary hydroxyls, “tails”, to twelve Rb+ tightly interconnected by twelve F- creating complex structure with accessible pores for potential gas adsorptions. | en |
dc.format.mimetype | application/pdf | |
dc.language | eng | |
dc.language.iso | eng | |
dc.publisher | American Chemical Society | |
dc.relation.ispartofseries | Crystal Growth and Design | |
dc.rights | In Copyright | |
dc.subject.other | cyclodextrin | |
dc.subject.other | sandwich-type complex | |
dc.subject.other | X-ray crystallography | |
dc.subject.other | metal-organic material | |
dc.subject.other | rubidium | |
dc.subject.other | silver | |
dc.title | Heads or Tails? Sandwich-Type Metallocomplexes of Hexakis(2,3-di-O-methyl)-α-cyclodextrin | |
dc.type | article | |
dc.identifier.urn | URN:NBN:fi:jyu-202005043023 | |
dc.contributor.laitos | Kemian laitos | fi |
dc.contributor.laitos | Department of Chemistry | en |
dc.contributor.oppiaine | Orgaaninen kemia | fi |
dc.contributor.oppiaine | Nanoscience Center | fi |
dc.contributor.oppiaine | Organic Chemistry | en |
dc.contributor.oppiaine | Nanoscience Center | en |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
dc.description.reviewstatus | peerReviewed | |
dc.format.pagerange | 4193-4199 | |
dc.relation.issn | 1528-7483 | |
dc.relation.numberinseries | 6 | |
dc.relation.volume | 20 | |
dc.type.version | acceptedVersion | |
dc.rights.copyright | © 2020 American Chemical Society | |
dc.rights.accesslevel | openAccess | fi |
dc.relation.grantnumber | 298817 | |
dc.format.content | fulltext | |
dc.rights.url | http://rightsstatements.org/page/InC/1.0/?language=en | |
dc.relation.doi | 10.1021/acs.cgd.0c00532 | |
dc.relation.funder | Research Council of Finland | en |
dc.relation.funder | Suomen Akatemia | fi |
jyx.fundingprogram | Postdoctoral Researcher, AoF | en |
jyx.fundingprogram | Tutkijatohtori, SA | fi |
jyx.fundinginformation | This project has received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie and is co-financed by the South Moravian Region under grant agreement No. 665860 (OJ and PZP). This publication reflects only the authors’ view and the EU is not responsible for any use that may be made of the information it contains. We thank to the Czech Science Foundation (Grant No. 16-05961S) and project CEITEC
2020 supported by the Ministry of Education, Youth, and Sports (Grant No. LQ1601). The work was supported from European Regional Development Fund-Project „MSCAfellow2@MUNI“ (No. CZ.02.2.69/0.0/0.0/18_070/0009846) (PJ). The authors gratefully acknowledge financial support from the Academy of Finland (RP grant no. 298817) and the University of Jyväskylä, Finland. Dr. Miroslava Bittová is gratefully acknowledged for measuring HRMS spectrum. | |
dc.type.okm | A1 | |