Unusual B4N2C2 Ligand in a Ruthenium Pseudo-Triple-Decker Sandwich Complex Displaying Three Reversible Electron-Transfer Steps
Ly, H., Tuononen, H., Parvez, M., & Roesler, R. (2008). Unusual B4N2C2 Ligand in a Ruthenium Pseudo-Triple-Decker Sandwich Complex Displaying Three Reversible Electron-Transfer Steps. Angewandte Chemie, International Edition, 47(2), 361-364. https://doi.org/10.1002/anie.200703556
Julkaistu sarjassa
Angewandte Chemie, International EditionPäivämäärä
2008Tekijänoikeudet
© 2008 Wiley-VCH Verlag GmbH & Co. This is a final draft version of an article whose final and definitive form has been published by Wiley. Published in this repository with the kind permission of the publisher.
Open, sesame: The reaction of a heterobicyclic pentalenediyl-like Me2Ph4B4N2C2 dianion with [{(C5Me5)RuCl}4] cleaves the N[BOND]N bond of the ligand and affords a pseudo-triple-decker sandwich complex containing a B4N2C2 middle deck (see picture). This eight-membered ring features nearly linear B-N-B moieties and brings the ruthenium centers unusually close. Cyclic voltammetry indicates efficient electron delocalization over the framework.
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WileyISSN Hae Julkaisufoorumista
1433-7851Julkaisu tutkimustietojärjestelmässä
https://converis.jyu.fi/converis/portal/detail/Publication/17432181