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dc.contributor.authorHicks, Jamie
dc.contributor.authorVasko, Petra
dc.contributor.authorGoicoechea, Jose Manuel
dc.contributor.authorAldridge, Simon
dc.date.accessioned2020-02-10T12:35:52Z
dc.date.available2020-02-10T12:35:52Z
dc.date.issued2019
dc.identifier.citationHicks, Jamie; Vasko, Petra; Goicoechea, Jose Manuel; Aldridge, Simon (2019). Reversible, room-temperature C-C bond activation of benzene by an isolable metal complex. Journal of the American Chemical Society, 141 (28), 11000-11003. DOI: 10.1021/jacs.9b05925
dc.identifier.otherCONVID_31276548
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/67793
dc.description.abstractThe activation of C-C bonds is of fundamental interest in the construction of complex molecules from petrochemical feedstocks. In the case of the archetypal aromatic hydrocarbon benzene, C-C cleavage is thermodynamically disfavoured, and is brought about only by transient highly reactive species generated in situ. Here we show that the oxidative addition of the C-C bond in benzene by an isolated metal complex is not only possible, but occurs at room temperature and reversibly at a single aluminium centre in [(NON)Al]- (where NON = 4,5-bis(2,6-diisopropylanilido)-2,7-di-tert-butyl-9,9-dimethylxanthene). Selectivity over C-H bond activation is achieved kinetically and allows for the generation of functionalized acyclic products from benzene.en
dc.format.mimetypeapplication/pdf
dc.languageeng
dc.publisherAmerican Chemical Society
dc.relation.ispartofseriesJournal of the American Chemical Society
dc.rightsIn Copyright
dc.subject.otherC-C bonds
dc.titleReversible, room-temperature C-C bond activation of benzene by an isolable metal complex
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-202002102040
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.description.reviewstatuspeerReviewed
dc.format.pagerange11000-11003
dc.relation.issn0002-7863
dc.relation.numberinseries28
dc.relation.volume141
dc.type.versionacceptedVersion
dc.rights.copyright© 2019 American Chemical Society
dc.rights.accesslevelopenAccessfi
dc.relation.grantnumber314794
dc.format.contentfulltext
dc.rights.urlhttp://rightsstatements.org/page/InC/1.0/?language=en
dc.relation.doi10.1021/jacs.9b05925
dc.relation.funderSuomen Akatemiafi
dc.relation.funderAcademy of Finlanden
jyx.fundingprogramTutkijatohtori, SAfi
jyx.fundingprogramPostdoctoral Researcher, AoFen
jyx.fundinginformationThe use of the University of Oxford Advanced Research Computing (ARC) facility is acknowledged. This work was supported by the Leverhulme Trust (grant number RP-2018-246, JH), the Oxford SCG Centre of Excellence and the Academy of Finland (PV, project number 314794).


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