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dc.contributor.authorHossain, Md. Kamal
dc.contributor.authorHaukka, Matti
dc.contributor.authorHänninen, Mikko M.
dc.contributor.authorLisensky, George C.
dc.contributor.authorPaturi, Petriina
dc.contributor.authorNordlander, Ebbe
dc.contributor.authorLehtonen, Ari
dc.date.accessioned2018-06-06T05:55:10Z
dc.date.available2020-08-02T21:35:10Z
dc.date.issued2018fi
dc.identifier.citationHossain, M. K., Haukka, M., Hänninen, M. M., Lisensky, G. C., Paturi, P., Nordlander, E., & Lehtonen, A. (2018). An experimental and theoretical study of a heptacoordinated tungsten(VI) complex of a noninnocent phenylenediamine bis(phenolate) ligand. <em>Inorganic Chemistry Communications</em>, 93, 149-152. <a href="https://doi.org/10.1016/j.inoche.2018.05.023">doi:10.1016/j.inoche.2018.05.023</a>fi
dc.identifier.otherTUTKAID_77683
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/58366
dc.description.abstract[W(N2O2)(HN2O2)] (H4N2O2 = N,N′-bis(3,5-di-tert-butyl-2-hydroxyphenyl)-1,2-phenylenediamine) with a noninnocent ligand was formed by reaction of the alkoxide precursor [W(eg)3] (eg = the 1,2-ethanediolate dianion) with two equivalents of ligand. The phenol groups on one of the ligands are completely deprotonated and the ligand coordinates in a tetradentate fashion, whereas the other ligand is tridentate with one phenol having an intact OH group. The molecular structure, magnetic measurements, EPR spectroscopy, and density functional theory calculations indicate that the complex is a stable radical with the odd electron situated on the tridentate amidophenoxide ligand. The formal oxidation state of the metal center is W(VI), with the paramagnetic properties being due to the unpaired electron on the ligand.fi
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.publisherElsevier BV
dc.relation.ispartofseriesInorganic Chemistry Communications
dc.rightsCC BY-NC-ND 4.0
dc.subject.otherexperimental and theoretical studyfi
dc.subject.otherheptacoordinated tungsten(VI) complexfi
dc.subject.othernoninnocent phenylenediamine bis(phenolate) ligandfi
dc.titleAn experimental and theoretical study of a heptacoordinated tungsten(VI) complex of a noninnocent phenylenediamine bis(phenolate) ligandfi
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201805282849
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemia
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2018-05-28T12:15:08Z
dc.description.reviewstatuspeerReviewed
dc.format.pagerange149-152
dc.relation.issn1387-7003
dc.relation.numberinseries0
dc.relation.volume93
dc.type.versionacceptedVersion
dc.rights.copyright© 2018 Elsevier B.V. All rights reserved.
dc.rights.accesslevelopenAccessfi
dc.format.contentfulltext
dc.rights.urlhttps://creativecommons.org/licenses/by-nc-nd/4.0/
dc.relation.doi10.1016/j.inoche.2018.05.023


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