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dc.contributor.authorTurunen, Lotta
dc.contributor.authorPan, FangFang
dc.contributor.authorBeyeh, Ngong Kodiah
dc.contributor.authorTrant, John F.
dc.contributor.authorRas, Robin H. A.
dc.contributor.authorRissanen, Kari
dc.date.accessioned2018-01-19T11:00:52Z
dc.date.available2018-12-06T22:35:45Z
dc.date.issued2018
dc.identifier.citationTurunen, L., Pan, F., Beyeh, N. K., Trant, J. F., Ras, R. H. A., & Rissanen, K. (2018). Bamboo-like Chained Cavities and Other Halogen-Bonded Complexes from Tetrahaloethynyl Cavitands with Simple Ditopic Halogen Bond Acceptors. <i>Crystal Growth and Design</i>, <i>18</i>(1), 513-520. <a href="https://doi.org/10.1021/acs.cgd.7b01517" target="_blank">https://doi.org/10.1021/acs.cgd.7b01517</a>
dc.identifier.otherCONVID_27408890
dc.identifier.otherTUTKAID_75998
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/56817
dc.description.abstractHalogen bonding provides a useful complement to hydrogen bonding and metal-coordination as a tool for organizing supramolecular systems. Resorcinarenes, tetrameric bowl-shaped cavitands, have been previously shown to function as efficient scaffolds for generating dimeric capsules in both solution and solid-phase, and complicated one-, two-, and three-dimensional frameworks in the solid phase. Tetrahaloethynyl resorcinarenes (bromide and iodide) position the halogen atoms in a very promising “crown-like” orientation for acting as organizing halogen-bond donors to help build capsules and higher-order networks. Symmetric divalent halogen bond acceptors including bipyridines, 1,4-dioxane, and 1,4-diazabicyclo[2.2.2]octane are very promising halogen bond accepting partners for creating these systems. This report describes the complex structures arising from combining these various systems including self-included dimers, herringbone-packed architectures enclosing medium (186 Å3) cavities, and a very intriguing bamboo-like one-dimensional rod with large (683 Å3) cavities between adjacent dimeric units. These various structures, all organized through host–host, host–acceptor, and host–solvent interactions highlight the emergent complexity of these types of complexes. As halogen bonds are weaker than hydrogen-bonds, the resulting architectures are harder to predict, and these results provide additional insight into the parameters requiring consideration when designing crystalline supramolecular systems using halogen-bonds as the core organizing principle.en
dc.languageeng
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.relation.ispartofseriesCrystal Growth and Design
dc.subject.otherhalogen-bonded complexes
dc.subject.otherhalogen bonds
dc.titleBamboo-like Chained Cavities and Other Halogen-Bonded Complexes from Tetrahaloethynyl Cavitands with Simple Ditopic Halogen Bond Acceptors
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201801151198
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineOrgaaninen kemiafi
dc.contributor.oppiaineNanoscience Centerfi
dc.contributor.oppiaineOrganic Chemistryen
dc.contributor.oppiaineNanoscience Centeren
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2018-01-15T16:51:16Z
dc.type.coarjournal article
dc.description.reviewstatuspeerReviewed
dc.format.pagerange513-520
dc.relation.issn1528-7483
dc.relation.numberinseries1
dc.relation.volume18
dc.type.versionacceptedVersion
dc.rights.copyright© 2017 American Chemical Society. This is a final draft version of an article whose final and definitive form has been published by ACS. Published in this repository with the kind permission of the publisher.
dc.rights.accesslevelopenAccessfi
dc.relation.grantnumber263256
dc.relation.grantnumber292746
dc.subject.ysokemia
dc.subject.ysoobligaatiot
dc.subject.ysohalogeenit
jyx.subject.urihttp://www.yso.fi/onto/yso/p1801
jyx.subject.urihttp://www.yso.fi/onto/yso/p18594
jyx.subject.urihttp://www.yso.fi/onto/yso/p4164
dc.relation.doi10.1021/acs.cgd.7b01517
dc.relation.funderSuomen Akatemiafi
dc.relation.funderSuomen Akatemiafi
dc.relation.funderAcademy of Finlanden
dc.relation.funderAcademy of Finlanden
jyx.fundingprogramAkatemiaprofessorin tehtävä, SAfi
jyx.fundingprogramAkatemiaprofessorin tutkimuskulut, SAfi
jyx.fundingprogramResearch post as Academy Professor, AoFen
jyx.fundingprogramResearch costs of Academy Professor, AoFen
jyx.fundinginformationThe authors gratefully acknowledge financial support from the Academy of Finland (K.R.: Grant Nos. 265328, 263256, and 292746; RHAR: Grant No. 272579), the University of Jyvaskyla, and the University of Windsor, Canada. This work was supported by the Program of Introducing Talents of Discipline to Universities of China (111 program, B17019) and the Academy of Finland through its Centres of Excellence Programme (HYBER 2014–2019).


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