| dc.contributor.author | LeBlanc, Francis A. | |
| dc.contributor.author | Decken, Andreas | |
| dc.contributor.author | Cameron, T. Stanley | |
| dc.contributor.author | Passmore, Jack | |
| dc.contributor.author | Rautiainen, Mikko | |
| dc.contributor.author | Whidden, Thomas K. | |
| dc.date.accessioned | 2018-01-15T11:04:44Z | |
| dc.date.available | 2018-01-15T11:04:44Z | |
| dc.date.issued | 2017 | |
| dc.identifier.citation | LeBlanc, F. A., Decken, A., Cameron, T. S., Passmore, J., Rautiainen, M., & Whidden, T. K. (2017). Synthesis, Characterization, and Properties of Weakly Coordinating Anions Based on tris-Perfluoro-tert-Butoxyborane. <i>Inorganic Chemistry</i>, <i>56</i>(2), 974-983. <a href="https://doi.org/10.1021/acs.inorgchem.6b02670" target="_blank">https://doi.org/10.1021/acs.inorgchem.6b02670</a> | |
| dc.identifier.other | CONVID_26558521 | |
| dc.identifier.other | TUTKAID_73039 | |
| dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/56730 | |
| dc.description.abstract | Abstract Image
A convenient method for the preparation of strongly Lewis acidic tris-perfluoro-tert-butoxyborane B(ORF)3 (1), (ORF = OC(CF3)3) was developed, and its X-ray structure was determined. 1 was used as a precursor, guided by density functional theory (DFT) calculations and volume-based thermodynamics, for the synthesis of [NEt4][NCB(ORF)3] (3) and [NMe4][FB(ORF)3] (5) and the novel large and weakly coordinating anion salts [Li 15-Crown-5][B(ORF)4] (2) and [NEt4][CN{B(ORF)3}2] (4). The stability of [B(ORF)4]− was compared with that of some related known weakly coordinating anions by appropriate DFT calculations. | |
| dc.language.iso | eng | |
| dc.publisher | American Chemical Society | |
| dc.relation.ispartofseries | Inorganic Chemistry | |
| dc.subject.other | boranes | |
| dc.subject.other | weakly coordinating anions | |
| dc.subject.other | Lewis acids | |
| dc.title | Synthesis, Characterization, and Properties of Weakly Coordinating Anions Based on tris-Perfluoro-tert-Butoxyborane | |
| dc.type | article | |
| dc.identifier.urn | URN:NBN:fi:jyu-201801121174 | |
| dc.contributor.laitos | Kemian laitos | fi |
| dc.contributor.laitos | Department of Chemistry | en |
| dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
| dc.contributor.oppiaine | Nanoscience Center | fi |
| dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
| dc.contributor.oppiaine | Nanoscience Center | en |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
| dc.date.updated | 2018-01-12T13:15:31Z | |
| dc.type.coar | journal article | |
| dc.description.reviewstatus | peerReviewed | |
| dc.format.pagerange | 974-983 | |
| dc.relation.issn | 0020-1669 | |
| dc.relation.numberinseries | 2 | |
| dc.relation.volume | 56 | |
| dc.type.version | acceptedVersion | |
| dc.rights.copyright | © American Chemical Society, 2017. This is a final draft version of an article whose final and definitive form has been published by American Chemical Society. Published in this repository with the kind permission of the publisher. | |
| dc.rights.accesslevel | openAccess | fi |
| dc.subject.yso | synteesi | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p8467 | |
| dc.relation.doi | 10.1021/acs.inorgchem.6b02670 | |
