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dc.contributor.authorLeBlanc, Francis A.
dc.contributor.authorDecken, Andreas
dc.contributor.authorCameron, T. Stanley
dc.contributor.authorPassmore, Jack
dc.contributor.authorRautiainen, Mikko
dc.contributor.authorWhidden, Thomas K.
dc.date.accessioned2018-01-15T11:04:44Z
dc.date.available2018-01-15T11:04:44Z
dc.date.issued2017
dc.identifier.citationLeBlanc, F. A., Decken, A., Cameron, T. S., Passmore, J., Rautiainen, M., & Whidden, T. K. (2017). Synthesis, Characterization, and Properties of Weakly Coordinating Anions Based on tris-Perfluoro-tert-Butoxyborane. <em>Inorganic Chemistry</em>, 56 (2), 974-983. <a href="https://doi.org/10.1021/acs.inorgchem.6b02670">doi:10.1021/acs.inorgchem.6b02670</a>
dc.identifier.otherTUTKAID_73039
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/56730
dc.description.abstractAbstract Image A convenient method for the preparation of strongly Lewis acidic tris-perfluoro-tert-butoxyborane B(ORF)3 (1), (ORF = OC(CF3)3) was developed, and its X-ray structure was determined. 1 was used as a precursor, guided by density functional theory (DFT) calculations and volume-based thermodynamics, for the synthesis of [NEt4][NCB(ORF)3] (3) and [NMe4][FB(ORF)3] (5) and the novel large and weakly coordinating anion salts [Li 15-Crown-5][B(ORF)4] (2) and [NEt4][CN{B(ORF)3}2] (4). The stability of [B(ORF)4]− was compared with that of some related known weakly coordinating anions by appropriate DFT calculations.
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.relation.ispartofseriesInorganic Chemistry
dc.subject.othersynthesis
dc.subject.otherboranes
dc.subject.otherweakly coordinating anions
dc.subject.otherLewis acids
dc.titleSynthesis, Characterization, and Properties of Weakly Coordinating Anions Based on tris-Perfluoro-tert-Butoxyborane
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201801121174
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemia
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2018-01-12T13:15:31Z
dc.type.coarjournal article
dc.description.reviewstatuspeerReviewed
dc.format.pagerange974-983
dc.relation.issn0020-1669
dc.relation.volume56
dc.type.versionacceptedVersion
dc.rights.copyright© American Chemical Society, 2017. This is a final draft version of an article whose final and definitive form has been published by American Chemical Society. Published in this repository with the kind permission of the publisher.
dc.rights.accesslevelopenAccessfi
dc.relation.doi10.1021/acs.inorgchem.6b02670


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