Synthesis, Characterization, and Properties of Weakly Coordinating Anions Based on tris-Perfluoro-tert-Butoxyborane
LeBlanc, F. A., Decken, A., Cameron, T. S., Passmore, J., Rautiainen, M., & Whidden, T. K. (2017). Synthesis, Characterization, and Properties of Weakly Coordinating Anions Based on tris-Perfluoro-tert-Butoxyborane. Inorganic Chemistry, 56 (2), 974-983. doi:10.1021/acs.inorgchem.6b02670
Published in
Inorganic ChemistryAuthors
Date
2017Discipline
Epäorgaaninen ja analyyttinen kemiaCopyright
© American Chemical Society, 2017. This is a final draft version of an article whose final and definitive form has been published by American Chemical Society. Published in this repository with the kind permission of the publisher.
Abstract Image
A convenient method for the preparation of strongly Lewis acidic tris-perfluoro-tert-butoxyborane B(ORF)3 (1), (ORF = OC(CF3)3) was developed, and its X-ray structure was determined. 1 was used as a precursor, guided by density functional theory (DFT) calculations and volume-based thermodynamics, for the synthesis of [NEt4][NCB(ORF)3] (3) and [NMe4][FB(ORF)3] (5) and the novel large and weakly coordinating anion salts [Li 15-Crown-5][B(ORF)4] (2) and [NEt4][CN{B(ORF)3}2] (4). The stability of [B(ORF)4]− was compared with that of some related known weakly coordinating anions by appropriate DFT calculations.
Publisher
American Chemical SocietyISSN Search the Publication Forum
0020-1669Metadata
Show full item recordCollections
Related items
Showing items with similar title or keywords.
-
Synthesis and Characterization of Zwitterionic Zn(II) and Cu(II) Coordination Compounds with Ring-substituted 2,2́-Biimidazole Derivatives
Tatikonda, Rajendhraprasad; Kalenius, Elina; Haukka, Matti (Elsevier BV, 2016)Zwitterionic coordination compounds with strongly asymmetrical charge distribution were synthesized and characterized. Ring-substituted biimidazoles were used as the primary ligands for Zn and Cu compounds. Formation of ... -
Construction of coordination polymers from semirigid ditopic 2,2´-Biimidazole derivatives : synthesis, crystal structures and characterization
Tatikonda, Rajendhraprasad; Bulatov, Evgeny; Kalenius, Elina; Haukka, Matti (American Chemical Society, 2017)Eight coordination polymers (CPs), {[Ag(L1)]ClO4}n (1), {[Ag(L2)1.5]ClO4·C2H3N}n (2a), {[Ag(L2)]ClO4}n (2b), [Zn(L1)Cl2]n (3), {[Zn(L2)Cl2]·CHCl3}n (4), {[Cu(L1)2Cl]Cl·H2O}n (5), [Cu2(L2)(μ-Cl)2]n (6), and [Cu4(L2)(μ-Cl)4]n ... -
Synthesis and investigation of coordinative properties of biimidazole-derived ligands
Bulatova, Margarita (2015)For this thesis a study of the coordination properties of biimidazole-based compounds was performed. The thesis is divided into two parts: literature part, where the chemistry and application of biimidazole and its derivatives ... -
Synthesis of isomorphous cobalt and nickel thiocyanate coordination compounds : effect of metals on compound properties
Hannachi, Anissa; Valkonen, Arto; Gómez García, Carlos J.; Rzaigui, Mohamed; Smirani, Wajda (Elsevier, 2019)The reaction of 2-methylpiperazine with the thiocyanate ligand and two transition metals leads to the production of two new isomorphous [ML2SCN4] where L is the 2-methylpiperazine and [M =Co (1), and Ni (2)], presenting ... -
Coordination Complexes of a Neutral 1,2,4-Benzotriazinyl Radical Ligand: Synthesis, Molecular and Electronic Structures, and Magnetic Properties
Morgan, Ian; Mansikkamäki, Akseli; Zissimou, Georgia A.; Koutentis, Panayoitis A.; Rouzières, Mathieu; Clérac, Rodolphe; Tuononen, Heikki (Wiley - VCH Verlag GmbH & Co. KGaA, 2015)A series of d-block metal complexes of the recently reported coordinating neutral radical ligand 1-phenyl-3-(pyrid-2-yl)-1,4-dihydro-1,2,4-benzotriazin-4-yl (1) was synthesized. The investigated systems contain the ...