Synthesis, Characterization, and Properties of Weakly Coordinating Anions Based on tris-Perfluoro-tert-Butoxyborane
LeBlanc, F. A., Decken, A., Cameron, T. S., Passmore, J., Rautiainen, J. M., & Whidden, T. K. (2017). Synthesis, Characterization, and Properties of Weakly Coordinating Anions Based on tris-Perfluoro-tert-Butoxyborane. Inorganic Chemistry, 56(2), 974-983. https://doi.org/10.1021/acs.inorgchem.6b02670
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Inorganic ChemistryDate
2017Discipline
Epäorgaaninen ja analyyttinen kemiaNanoscience CenterInorganic and Analytical ChemistryNanoscience CenterCopyright
© American Chemical Society, 2017. This is a final draft version of an article whose final and definitive form has been published by American Chemical Society. Published in this repository with the kind permission of the publisher.
A convenient method for the preparation of strongly Lewis acidic tris-perfluoro-tert-butoxyborane B(ORF)3 (1), (ORF = OC(CF3)3) was developed, and its X-ray structure was determined. 1 was used as a precursor, guided by density functional theory (DFT) calculations and volume-based thermodynamics, for the synthesis of [NEt4][NCB(ORF)3] (3) and [NMe4][FB(ORF)3] (5) and the novel large and weakly coordinating anion salts [Li 15-Crown-5][B(ORF)4] (2) and [NEt4][CN{B(ORF)3}2] (4). The stability of [B(ORF)4]− was compared with that of some related known weakly coordinating anions by appropriate DFT calculations.
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American Chemical SocietyISSN Search the Publication Forum
0020-1669Keywords
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https://converis.jyu.fi/converis/portal/detail/Publication/26558521
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We thank the Natural Sciences and Engineering Research Council (NSERC) of Canada, the Academy of Finland (Grant No. 253400), and Emil Aaltonen Foundation for funding this project. ACEnet, the regional high-performance computing consortium for universities in Atlantic Canada, and CSC-IT Center for Science, Ltd., in Finland are acknowledged for providing computational resources. We acknowledge and ...
