| dc.contributor.author | LeBlanc, Francis A. | |
| dc.contributor.author | Decken, Andreas | |
| dc.contributor.author | Cameron, T. Stanley | |
| dc.contributor.author | Passmore, Jack | |
| dc.contributor.author | Rautiainen, J. Mikko | |
| dc.contributor.author | Whidden, Thomas K. | |
| dc.date.accessioned | 2018-01-15T11:04:44Z | |
| dc.date.available | 2018-01-15T11:04:44Z | |
| dc.date.issued | 2017 | |
| dc.identifier.citation | LeBlanc, F. A., Decken, A., Cameron, T. S., Passmore, J., Rautiainen, J. M., & Whidden, T. K. (2017). Synthesis, Characterization, and Properties of Weakly Coordinating Anions Based on tris-Perfluoro-tert-Butoxyborane. <i>Inorganic Chemistry</i>, <i>56</i>(2), 974-983. <a href="https://doi.org/10.1021/acs.inorgchem.6b02670" target="_blank">https://doi.org/10.1021/acs.inorgchem.6b02670</a> | |
| dc.identifier.other | CONVID_26558521 | |
| dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/56730 | |
| dc.description.abstract | A convenient method for the preparation of strongly Lewis acidic tris-perfluoro-tert-butoxyborane B(ORF)3 (1), (ORF = OC(CF3)3) was developed, and its X-ray structure was determined. 1 was used as a precursor, guided by density functional theory (DFT) calculations and volume-based thermodynamics, for the synthesis of [NEt4][NCB(ORF)3] (3) and [NMe4][FB(ORF)3] (5) and the novel large and weakly coordinating anion salts [Li 15-Crown-5][B(ORF)4] (2) and [NEt4][CN{B(ORF)3}2] (4). The stability of [B(ORF)4]− was compared with that of some related known weakly coordinating anions by appropriate DFT calculations. | en |
| dc.language.iso | eng | |
| dc.publisher | American Chemical Society | |
| dc.relation.ispartofseries | Inorganic Chemistry | |
| dc.subject.other | boranes | |
| dc.subject.other | weakly coordinating anions | |
| dc.subject.other | Lewis acids | |
| dc.subject.other | Anions | |
| dc.subject.other | Cations | |
| dc.subject.other | Enthalpy | |
| dc.subject.other | Salts | |
| dc.subject.other | Solvents | |
| dc.title | Synthesis, Characterization, and Properties of Weakly Coordinating Anions Based on tris-Perfluoro-tert-Butoxyborane | |
| dc.type | research article | |
| dc.identifier.urn | URN:NBN:fi:jyu-201801121174 | |
| dc.contributor.laitos | Kemian laitos | fi |
| dc.contributor.laitos | Department of Chemistry | en |
| dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
| dc.contributor.oppiaine | Nanoscience Center | fi |
| dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
| dc.contributor.oppiaine | Nanoscience Center | en |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
| dc.date.updated | 2018-01-12T13:15:31Z | |
| dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
| dc.description.reviewstatus | peerReviewed | |
| dc.format.pagerange | 974-983 | |
| dc.relation.issn | 0020-1669 | |
| dc.relation.numberinseries | 2 | |
| dc.relation.volume | 56 | |
| dc.type.version | acceptedVersion | |
| dc.rights.copyright | © American Chemical Society, 2017. This is a final draft version of an article whose final and definitive form has been published by American Chemical Society. Published in this repository with the kind permission of the publisher. | |
| dc.rights.accesslevel | openAccess | fi |
| dc.type.publication | article | |
| dc.subject.yso | anionit | |
| dc.subject.yso | kemialliset sidokset | |
| dc.subject.yso | synteesi | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p27229 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p10130 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p8467 | |
| dc.relation.doi | 10.1021/acs.inorgchem.6b02670 | |
| jyx.fundinginformation | We thank the Natural Sciences and Engineering Research Council (NSERC) of Canada, the Academy of Finland (Grant No. 253400), and Emil Aaltonen Foundation for funding this project. ACEnet, the regional high-performance computing consortium for universities in Atlantic Canada, and CSC-IT Center for Science, Ltd., in Finland are acknowledged for providing computational resources. We acknowledge and express our gratitude to Dr. Yi Ren and the University of Calgary for the performance of DSC measurements. | |
| dc.type.okm | A1 | |
