Tridentate C–I⋯O−–N+ halogen bonds
Topic, F., Puttreddy, R., Rautiainen, M., Tuononen, H., & Rissanen, K. (2017). Tridentate C–I⋯O−–N+ halogen bonds. CrystEngComm, 19 (34), 4960-4963. doi:10.1039/c7ce01381g
© The Royal Society of Chemistry 2017. This is a final draft version of an article whose final and definitive form has been published by RSC. Published in this repository with the kind permission of the publisher.
The X-ray structures of the first co-crystals where the three oxygen lone pairs in N-oxides are fully utilized for tridentate C–I⋯O−–N+ halogen bonding with 1,ω-diiodoperfluoroalkanes are reported, studied computationally, and compared with the corresponding silver(I) N-oxide complexes.