Tridentate C–I⋯O−–N+ halogen bonds
Topic, F., Puttreddy, R., Rautiainen, M., Tuononen, H., & Rissanen, K. (2017). Tridentate C–I⋯O−–N+ halogen bonds. CrystEngComm, 19(34), 4960-4963. https://doi.org/10.1039/c7ce01381g
DisciplineEpäorgaaninen ja analyyttinen kemiaKemiaOrgaaninen kemiaInorganic and Analytical ChemistryChemistryOrganic Chemistry
© The Royal Society of Chemistry 2017. This is a final draft version of an article whose final and definitive form has been published by RSC. Published in this repository with the kind permission of the publisher.
The X-ray structures of the first co-crystals where the three oxygen lone pairs in N-oxides are fully utilized for tridentate C–I⋯O−–N+ halogen bonding with 1,ω-diiodoperfluoroalkanes are reported, studied computationally, and compared with the corresponding silver(I) N-oxide complexes.
PublisherRoyal Society of Chemistry
Publication in research information system
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Related funder(s)Academy of Finland
Funding program(s)Research post as Academy Professor, AoF; Research costs of Academy Professor, AoF; Postdoctoral Researcher, AoF
Additional information about fundingThe authors gratefully acknowledge financial support from the Academy of Finland (RP: grant no. 298817, KR: grant no. 265328, 263256 and 292746) and the Emil Aaltonen Foundation (HMT), grants of computer capacity from the Finnish Grid and Cloud Infrastructure (urn:nbn:fi:research-infras-2016072533), and the University of Jyväskylä.
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