Tridentate C–I⋯O−–N+ halogen bonds

Topic, Filip; Puttreddy, Rakesh; Rautiainen, J. Mikko; Tuononen, Heikki; Rissanen, Kari

doi:10.1039/c7ce01381g

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Topic, F., Puttreddy, R., Rautiainen, J. M., Tuononen, H., & Rissanen, K. (2017). Tridentate C–I⋯O−–N+ halogen bonds. CrystEngComm, 19(34), 4960-4963. https://doi.org/10.1039/c7ce01381g

Published in

CrystEngComm

Authors

Topic, Filip |

Puttreddy, Rakesh |

Rautiainen, J. Mikko |

Tuononen, Heikki |

Rissanen, Kari

Date

2017

Discipline

Epäorgaaninen ja analyyttinen kemia Kemia Orgaaninen kemia Inorganic and Analytical Chemistry Chemistry Organic Chemistry

Copyright

© The Royal Society of Chemistry 2017. This is a final draft version of an article whose final and definitive form has been published by RSC. Published in this repository with the kind permission of the publisher.

The X-ray structures of the first co-crystals where the three oxygen lone pairs in N-oxides are fully utilized for tridentate C–I⋯O−–N+ halogen bonding with 1,ω-diiodoperfluoroalkanes are reported, studied computationally, and compared with the corresponding silver(I) N-oxide complexes.

Publisher

Royal Society of Chemistry

ISSN Search the Publication Forum

1466-8033

Related funder(s)

Research Council of Finland

Funding program(s)

Research post as Academy Professor, AoF; Research costs of Academy Professor, AoF; Postdoctoral Researcher, AoF

Additional information about funding

The authors gratefully acknowledge financial support from the Academy of Finland (RP: grant no. 298817, KR: grant no. 265328, 263256 and 292746) and the Emil Aaltonen Foundation (HMT), grants of computer capacity from the Finnish Grid and Cloud Infrastructure (urn:nbn:fi:research-infras-2016072533), and the University of Jyväskylä.