dc.contributor.author | Turunen, Lotta | |
dc.contributor.author | Peuronen, Anssi | |
dc.contributor.author | Forsblom, Samu | |
dc.contributor.author | Kalenius, Elina | |
dc.contributor.author | Lahtinen, Manu | |
dc.contributor.author | Rissanen, Kari | |
dc.date.accessioned | 2017-09-13T09:00:56Z | |
dc.date.available | 2018-07-29T21:35:43Z | |
dc.date.issued | 2017 | |
dc.identifier.citation | Turunen, L., Peuronen, A., Forsblom, S., Kalenius, E., Lahtinen, M., & Rissanen, K. (2017). Tetrameric and Dimeric [N∙∙∙I+∙∙∙N] Halogen-Bonded Supramolecular Cages. <i>Chemistry: A European Journal</i>, <i>23</i>(48), 11714-11718. <a href="https://doi.org/10.1002/chem.201702655" target="_blank">https://doi.org/10.1002/chem.201702655</a> | |
dc.identifier.other | CONVID_27080527 | |
dc.identifier.other | TUTKAID_74222 | |
dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/55340 | |
dc.description.abstract | Tripodal N‐donor ligands are used to form halogen‐bonded assemblies via structurally analogous Ag+‐complexes. Selective formation of discrete tetrameric I6L4 and dimeric I3L2 halonium cages, wherein multiple [N⋅⋅⋅I+⋅⋅⋅N] halogen bonds are used in concert, can be achieved by using sterically rigidified cationic tris(1‐methyl‐1‐azonia‐4‐azabicyclo[2.2.2]octane)‐mesitylene ligand, L1(PF6)3, and flexible ligand 1,3,5‐tris(imidazole‐1‐ylmethyl)‐2,4,6‐trimethylbenzene, L2, respectively. The iodonium cages, I6L14(PF6)18 and I3L22(PF6)3, were obtained through the [N⋅⋅⋅Ag+⋅⋅⋅N]→ [N⋅⋅⋅I+⋅⋅⋅N] cation exchange reaction between the corresponding Ag6L14(PF6)18 and Ag3L22(PF6)3 coordination cages, prepared as intermediates, and I2. The synthesized metallo‐ and halonium cages were studied in solution by NMR, in gas phase by ESI‐MS and in the solid‐state by single crystal X‐ray diffraction. | en |
dc.language.iso | eng | |
dc.publisher | Wiley - VCH Verlag GmbH & Co. KGaA | |
dc.relation.ispartofseries | Chemistry: A European Journal | |
dc.subject.other | halogen bonds | |
dc.subject.other | supramolecular cages | |
dc.title | Tetrameric and Dimeric [N∙∙∙I+∙∙∙N] Halogen-Bonded Supramolecular Cages | |
dc.type | article | |
dc.identifier.urn | URN:NBN:fi:jyu-201709113698 | |
dc.contributor.laitos | Kemian laitos | fi |
dc.contributor.laitos | Department of Chemistry | en |
dc.contributor.oppiaine | Orgaaninen kemia | fi |
dc.contributor.oppiaine | Nanoscience Center | fi |
dc.contributor.oppiaine | Organic Chemistry | en |
dc.contributor.oppiaine | Nanoscience Center | en |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
dc.date.updated | 2017-09-11T09:15:11Z | |
dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
dc.description.reviewstatus | peerReviewed | |
dc.format.pagerange | 11714-11718 | |
dc.relation.issn | 0947-6539 | |
dc.relation.numberinseries | 48 | |
dc.relation.volume | 23 | |
dc.type.version | acceptedVersion | |
dc.rights.copyright | © 2017 Wiley-VCH Verlag GmbH &Co. This is a final draft version of an article whose final and definitive form has been published by Wiley-VCH. Published in this repository with the kind permission of the publisher. | |
dc.rights.accesslevel | openAccess | fi |
dc.relation.grantnumber | 263256 | |
dc.relation.grantnumber | 292746 | |
dc.relation.grantnumber | 277250 | |
dc.relation.grantnumber | 278743 | |
dc.relation.grantnumber | 284562 | |
dc.relation.doi | 10.1002/chem.201702655 | |
dc.relation.funder | Suomen Akatemia | fi |
dc.relation.funder | Suomen Akatemia | fi |
dc.relation.funder | Suomen Akatemia | fi |
dc.relation.funder | Suomen Akatemia | fi |
dc.relation.funder | Suomen Akatemia | fi |
dc.relation.funder | Research Council of Finland | en |
dc.relation.funder | Research Council of Finland | en |
dc.relation.funder | Research Council of Finland | en |
dc.relation.funder | Research Council of Finland | en |
dc.relation.funder | Research Council of Finland | en |
jyx.fundingprogram | Akatemiaprofessorin tehtävä, SA | fi |
jyx.fundingprogram | Akatemiaprofessorin tutkimuskulut, SA | fi |
jyx.fundingprogram | Akatemiahanke, SA | fi |
jyx.fundingprogram | Akatemiatutkija, SA | fi |
jyx.fundingprogram | Akatemiatutkijan tutkimuskulut, SA | fi |
jyx.fundingprogram | Research post as Academy Professor, AoF | en |
jyx.fundingprogram | Research costs of Academy Professor, AoF | en |
jyx.fundingprogram | Academy Project, AoF | en |
jyx.fundingprogram | Academy Research Fellow, AoF | en |
jyx.fundingprogram | Research costs of Academy Research Fellow, AoF | en |
jyx.fundinginformation | The authors kindly acknowledge the Academy of Finland (K.R.: Nos. 263256, 265328, 292746; E.K.: Nos. 284562 and 278743; M.L.: No. 277250). | |
dc.type.okm | A1 | |