Show simple item record

dc.contributor.authorKiesilä, Anniina
dc.contributor.authorKivijärvi, Lauri
dc.contributor.authorBeyeh, Ngong Kodiah
dc.contributor.authorMoilanen, Jani
dc.contributor.authorGroessl, Michael
dc.contributor.authorRothe, Tatiana
dc.contributor.authorGötz, Sven
dc.contributor.authorTopic, Filip
dc.contributor.authorRissanen, Kari
dc.contributor.authorLützen, Arne
dc.contributor.authorKalenius, Elina
dc.date.accessioned2017-08-31T08:24:42Z
dc.date.available2018-07-04T21:35:30Z
dc.date.issued2017
dc.identifier.citationKiesilä, A., Kivijärvi, L., Beyeh, N. K., Moilanen, J., Groessl, M., Rothe, T., Götz, S., Topic, F., Rissanen, K., Lützen, A., & Kalenius, E. (2017). Simultaneous Endo- and Exo-Complex Formation of Pyridine[4]arene Dimer with Neutral and Anionic Guests. <i>Angewandte Chemie International Edition</i>, <i>56</i>(36), 10942-10946. <a href="https://doi.org/10.1002/anie.201704054" target="_blank">https://doi.org/10.1002/anie.201704054</a>
dc.identifier.otherCONVID_27105520
dc.identifier.otherTUTKAID_74366
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/55226
dc.description.abstractThe formation of complexes between hexafluorophosphate (PF6−) and tetraisobutyloctahydroxypyridine[4]arene has been thoroughly studied in the gas phase (ESI‐QTOF‐MS, IM‐MS, DFT calculations), in the solid state (X‐ray crystallography), and in chloroform solution (1H, 19F, and DOSY NMR spectroscopy). In all states of matter, simultaneous endo complexation of solvent molecules and exo complexation of a PF6− anion within a pyridine[4]arene dimer was observed. While similar ternary complexes are often observed in the solid state, this is a unique example of such behavior in the gas phase.en
dc.language.isoeng
dc.publisherWiley-VCH
dc.relation.ispartofseriesAngewandte Chemie International Edition
dc.subject.othercoordination complex
dc.subject.otherhexafluorophosphate
dc.titleSimultaneous Endo- and Exo-Complex Formation of Pyridine[4]arene Dimer with Neutral and Anionic Guests
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201708303616
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineOrgaaninen kemiafi
dc.contributor.oppiaineNanoscience Centerfi
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.contributor.oppiaineOrganic Chemistryen
dc.contributor.oppiaineNanoscience Centeren
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2017-08-30T12:15:11Z
dc.type.coarjournal article
dc.description.reviewstatuspeerReviewed
dc.format.pagerange10942-10946
dc.relation.issn1433-7851
dc.relation.numberinseries36
dc.relation.volume56
dc.type.versionacceptedVersion
dc.rights.copyright© 2017 Wiley-VCH Verlag GmbH & Co. This is a final draft version of an article whose final and definitive form has been published by Wiley. Published in this repository with the kind permission of the publisher.
dc.rights.accesslevelopenAccessfi
dc.relation.grantnumber285855
dc.relation.grantnumber278743
dc.relation.grantnumber292746
dc.relation.grantnumber263256
dc.relation.grantnumber284562
dc.subject.ysoaromaattiset hiilivedyt
jyx.subject.urihttp://www.yso.fi/onto/yso/p23503
dc.relation.doi10.1002/anie.201704054
dc.relation.funderSuomen Akatemiafi
dc.relation.funderSuomen Akatemiafi
dc.relation.funderSuomen Akatemiafi
dc.relation.funderSuomen Akatemiafi
dc.relation.funderSuomen Akatemiafi
dc.relation.funderAcademy of Finlanden
dc.relation.funderAcademy of Finlanden
dc.relation.funderAcademy of Finlanden
dc.relation.funderAcademy of Finlanden
dc.relation.funderAcademy of Finlanden
jyx.fundingprogramTutkijatohtori, SAfi
jyx.fundingprogramAkatemiatutkijan tehtävä, SAfi
jyx.fundingprogramAkatemiaprofessorin tutkimuskulut, SAfi
jyx.fundingprogramAkatemiaprofessorin tehtävä, SAfi
jyx.fundingprogramAkatemiatutkijan tutkimuskulut, SAfi
jyx.fundingprogramPostdoctoral Researcher, AoFen
jyx.fundingprogramResearch post as Academy Research Fellow, AoFen
jyx.fundingprogramResearch costs of Academy Professor, AoFen
jyx.fundingprogramResearch post as Academy Professor, AoFen
jyx.fundingprogramResearch costs of Academy Research Fellow, AoFen
jyx.fundinginformationThe Academy of Finland (projects 263256, 265328, and 292746 to K.R.; projects 284562 and 278743 to E.K.; project 285855 to J.O.M.), the University of Jyväskylä, and Aalto University are gratefully acknowledged for financial support. This work was supported by the Academy of Finland through its Centres of Excellence Program (HYBER 2014‐2019). We thank Antti Halla for preliminary experiments. J.O.M. acknowledges the CSC–IT Center for Science, Finland and Prof. Heikki M. Tuononen for computational resources.


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record