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dc.contributor.authorKiesilä, Anniina
dc.contributor.authorKivijärvi, Lauri
dc.contributor.authorBeyeh, Ngong Kodiah
dc.contributor.authorMoilanen, Jani
dc.contributor.authorGroessl, Michael
dc.contributor.authorRothe, Tatiana
dc.contributor.authorGötz, Sven
dc.contributor.authorTopic, Filip
dc.contributor.authorRissanen, Kari
dc.contributor.authorLützen, Arne
dc.contributor.authorKalenius, Elina
dc.date.accessioned2017-08-31T08:24:42Z
dc.date.available2018-07-04T21:35:30Z
dc.date.issued2017
dc.identifier.citationKiesilä, A., Kivijärvi, L., Beyeh, N. K., Moilanen, J., Groessl, M., Rothe, T., . . . Kalenius, E. (2017). Simultaneous Endo- and Exo-Complex Formation of Pyridine[4]arene Dimer with Neutral and Anionic Guests. <em>Angewandte Chemie International Edition</em>, 56 (36), 10942-10946. <a href="https://doi.org/10.1002/anie.201704054">doi:10.1002/anie.201704054</a>
dc.identifier.otherTUTKAID_74366
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/55226
dc.description.abstractThe formation of complexes between hexafluorophosphate (PF6−) and tetraisobutyloctahydroxypyridine[4]arene has been thoroughly studied in the gas phase (ESI-QTOF-MS, IM-MS, DFT calculations), in the solid state (X-ray crystallography), and in chloroform solution (1H, 19F, and DOSY NMR spectroscopy). In all states of matter, simultaneous endo complexation of solvent molecules and exo complexation of a PF6− anion within a pyridine[4]arene dimer was observed. While similar ternary complexes are often observed in the solid state, this is a unique example of such behavior in the gas phase.
dc.language.isoeng
dc.publisherWiley-VCH
dc.relation.ispartofseriesAngewandte Chemie International Edition
dc.subject.othercoordination complex
dc.subject.otherhexafluorophosphate
dc.subject.otheraromatic hydrocarbons
dc.titleSimultaneous Endo- and Exo-Complex Formation of Pyridine[4]arene Dimer with Neutral and Anionic Guests
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201708303616
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemia
dc.contributor.oppiaineOrgaaninen kemia
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2017-08-30T12:15:11Z
dc.type.coarjournal article
dc.description.reviewstatuspeerReviewed
dc.format.pagerange10942-10946
dc.relation.issn1433-7851
dc.relation.volume56
dc.type.versionacceptedVersion
dc.rights.copyright© 2017 Wiley-VCH Verlag GmbH & Co. This is a final draft version of an article whose final and definitive form has been published by Wiley. Published in this repository with the kind permission of the publisher.
dc.rights.accesslevelopenAccessfi
dc.relation.doi10.1002/anie.201704054


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