From isolated 1H-pyrazole cryptand anion receptors to hybrid inorganic–organic 1D helical polymeric anion receptors

Pitarch-Jarque, Javier; Belda, Raquel; García-España, Laura; Llinares, José M.; Pan, Fangfang; Rissanen, Kari; Navarro, Pilar; García-España, Enrique

doi:10.1039/c5dt00763a

Final Draft

Katso/Avaa

903.2 Kb

Lataukset:

Show download details Hide download details

Pitarch-Jarque, J., Belda, R., García-España, L., Llinares, J. M., Pan, F., Rissanen, K., Navarro, P., & García-España, E. (2015). From isolated 1H-pyrazole cryptand anion receptors to hybrid inorganic–organic 1D helical polymeric anion receptors. Dalton transactions, 44(17), 7761-7764. https://doi.org/10.1039/c5dt00763a

Julkaistu sarjassa

Dalton transactions

Tekijät

Pitarch-Jarque, Javier |

Belda, Raquel |

García-España, Laura |

Llinares, José M. |

Pan, Fangfang |

Rissanen, Kari |

Navarro, Pilar |

García-España, Enrique

Päivämäärä

2015

Oppiaine

Orgaaninen kemia Nanoscience Center Organic Chemistry Nanoscience Center

Tekijänoikeudet

© The Royal Society of Chemistry, 2015. This is a final draft version of an article whose final and definitive form has been published by RSC. Published in this repository with the kind permission of the publisher.

We report on a novel 1-D helical coordination polymer formed by protonated polyamine 1H-pyrazole cryptands interconnected by Cu2+ metal ions able to encapsulate anionic species behaving as a multianion receptor. Switching from the monomeric to the polymeric receptor is activated by metal ions and pH.

Julkaisija

R S C Publications

ISSN Hae Julkaisufoorumista

1477-9226

Näytetään aineistoja, joilla on samankaltainen nimeke tai asiasanat.

Molecular and supramolecular structures of self-assembled Cu(II) and Co(II) complexes with 4,4’-[6-(3,5-dimethyl-1H-pyrazol-1-yl)-1,3,5-triazine-2,4-diyl]dimorpholine ligand

Soliman, Saied M.; Haukka, Matti; Al-Rasheed, Hessa H.; El-Faham, Ayman (Elsevier, 2020)

The molecular and supramolecular structures of [Cu(PTM)Cl2]*0.75MeOH (1), [Co(PTM)Cl2]; (2A) and [Co(PTM)Cl2(EtOH)]; (2B) complexes, where PTM is 4,4’-[6-(3,5-dimethyl-1H-pyrazol-1-yl)-1,3,5-triazine-2,4-diyl]dimorpholine, ...
A second monoclinic polymorph of 2-(3,5-dimethyl-1H-pyrazol-1-yl)-2-hydroxyimino-N'-[1-(pyridin-2-yl)ethylidene]acetohydrazide

Plutenko, M. O.; Lampeka, R. D.; Haukka, Matti; Nordlander, E. (Wiley-Blackwell Publishing, Inc., 2013)

[Introduction] The title compound, C 14 H 16 N 6 O 2 , is a second monoclinic polymorph of 2-[1-(3,5-dimethyl)pyrazolyl]-2-hydroxyimino- N 0 -[1-(2-pyridyl)ethylidene] acetohydrazide, with two crystal- lographically ...
A New 1D Ni (II) Coordination Polymer of s-Triazine Type Ligand and Thiocyanate as Linker via Unexpected Hydrolysis of 2,4-Bis(3,5-dimethyl-1H-pyrazol-1-yl)-6-methoxy-1,3,5-triazine

Dahlous, Kholood A.; Soliman, Saied M.; Haukka, Matti; El-Faham, Ayman; Massoud, Raghdaa A. (MDPI AG, 2023)

A new 1D Ni(II) coordination polymer was synthesized by the reaction of NiSO4·6H2O with 2,4-bis(3,5-dimethyl-1H-pyrazol-1-yl)-6-methoxy-1,3,5-triazine (BPT) and SCN− as a linker in an acidic medium by heating under reflux ...
2-(3,5-Dimethyl-1H-pyrazol-1-yl)-2-hydroxyimino-N0-[1-(pyridin-2-yl)ethylethylidene]

Plutenko, Maxym O.; Lampeka, Rostislav D.; Haukka, Matti; Nordlander, Ebbe (Wiley-Blackwell, 2012)

In the title compound, C14H16N6O2, the dihedral angles formed by the mean plane of the acetohydrazide group [maximum deviation 0.0629 (12) A˚ ] with the pyrazole and pyridine rings are 81.62 (6) and 38.38 (4) respectively. ...
Highlighting non-covalent interactions to molecular structure, electronic and vibrational spectra in a new hybrid organic–inorganic cobalt complexes : Synthesis, characterization, experimental and computational studies

Makhlouf, Jawher; El Bakri, Youness; Lai, Chin-Hung; Valkonen, Arto; Abuelizz, Hatem A.; Al-Salahi, Rashad; Sta, Wajda Smirani (Elsevier, 2025)

The cobalt (II) complexes have been synthesized from the reaction of the cationic entities (1-(2-methoxyphenyl) piperazine and the 1-(4-nitrophenyl) piperazine with metallic salt CoCl2·6H2O, then processing the evaporation ...