From isolated 1H-pyrazole cryptand anion receptors to hybrid inorganic–organic 1D helical polymeric anion receptors
Pitarch-Jarque, J., Belda, R., García-España, L., Llinares, J. M., Pan, F., Rissanen, K., . . . , & García-España, E. (2015). From isolated 1H-pyrazole cryptand anion receptors to hybrid inorganic–organic 1D helical polymeric anion receptors. Dalton transactions, 44 (17), 7761-7764. doi:10.1039/c5dt00763a
Published in
Dalton transactionsDate
2015Discipline
Orgaaninen kemiaCopyright
© The Royal Society of Chemistry, 2015. This is a final draft version of an article whose final and definitive form has been published by RSC. Published in this repository with the kind permission of the publisher.
We report on a novel 1-D helical coordination polymer formed
by protonated polyamine 1H-pyrazole cryptands interconnected
by Cu2+ metal ions able to encapsulate anionic species
behaving as a multianion receptor. Switching from the
monomeric to the polymeric receptor is activated by metal ions
and pH.