Self-assembly of a M4L6 complex with unexpected S4 symmetry
Giri, C., Topic, F., Mal, P., & Rissanen, K. (2014). Self-assembly of a M4L6 complex with unexpected S4 symmetry. Dalton transactions, 43(48), 17889-17892. https://doi.org/10.1039/C4DT02754J
Published in
Dalton transactionsDate
2014Copyright
© The Royal Society of Chemistry 2014. This is a final draft version of an article whose final and definitive form has been published by RSC. Published in this repository with the kind permission of the publisher.
Using 1,4-diaminobenzene and 2-formylpyridine as simple
building blocks results in a 1D ligand (rod, L2) to 2D (M4L4
grid, C1) to 3D (S4
symmetrical M4L6, C2) complexes upon
sequential addition of Cu(I) and Fe(II) ions. The complex C2
can be seen as the smallest possible pseudo-tetrahedron with
S4
symmetry.
Publisher
R S C PublicationsISSN Search the Publication Forum
1477-9226Publication in research information system
https://converis.jyu.fi/converis/portal/detail/Publication/23983822
Metadata
Show full item recordCollections
Related items
Showing items with similar title or keywords.
-
One‐pot synthesis of [2+2]‐helicate‐like macrocycle and 2+4‐μ4‐oxo tetranuclear open frame complexes : Chiroptical properties and asymmetric oxidative coupling of 2‐naphthols
Chinnaraja, E.; Arunachalam, R.; Pillai, R. S.; Peuronen, A.; Rissanen, K.; Subramanian, P. S. (John Wiley & Sons, 2020)Synthesis of binuclear Cu(II) terminally closed [2+2]‐ double‐stranded helicate‐like macrocycles 1, 1′,1″, 2, 2′, 2″ and 2+4‐μ4‐oxo tetranuclear open frame complexes 3, 3′, 3″, 4, 4′, 4″ are established. Adapting one‐pot ... -
Molecular, Supramolecular Structures Combined with Hirshfeld and DFT Studies of Centrosymmetric M(II)-azido {M=Ni(II), Fe(II) or Zn(II)} Complexes of 4-Benzoylpyridine
Abu-Youssef, Morsy A. M.; Langer, Vratislav; Barakat, Assem; Haukka, Matti; Soliman, Saied M. (MDPI AG, 2021)The supramolecular structures of the three metal (II) azido complexes [Fe(4bzpy)4(N3)2]; 1, [Ni(4bzpy)4(N3)2]; 2 and [Zn(4bzpy)2(N3)2]n; 3 with 4-benzoylpyridine (4bzpy) were presented. All complexes contain hexa-coordinated ... -
Hyper-CEST NMR of metal organic polyhedral cages reveals hidden diastereomers with diverse guest exchange kinetics
Jayapaul, Jabadurai; Komulainen, Sanna; Zhivonitko, Vladimir V.; Mareš, Jiří; Giri, Chandan; Rissanen, Kari; Lantto, Perttu; Telkki, Ville-Veikko; Schröder, Leif (Nature Publishing Group, 2022)Guest capture and release are important properties of self-assembling nanostructures. Over time, a significant fraction of guests might engage in short-lived states with different symmetry and stereoselectivity and transit ... -
Studies of two-dimensional and three-dimensional phononic crystal structures
Tian, Yolan (University of Jyväskylä, 2016)This thesis focuses on studying phononic crystal structures. More specifically, it is aimed at fabrication and measurement of thermal properties of two-dimensional (2D) periodic microstructures and three-dimensional (3D) ... -
Synthesis, X-ray Crystal Structure and Antimicrobial Activity of Unexpected Trinuclear Cu(II) Complex from s-Triazine-Based Di-Compartmental Ligand via Self-Assembly
Soliman, M. Saied; Lasri, Jamal; Haukka, Matti; Sholkamy, N. Essam; Al-Rasheed, H. Hessa; El-Faham, Ayman (MDPI, 2019)The synthesis and X-ray crystal structure of the trinuclear [Cu3(HL)(Cl)2(NO3)(H2O)5](NO3)2 complex of the s-triazine-based di-compartmental ligand, 2-methoxy-4,6-bis(2-(pyridin-2-ylmsethylene)hydrazinyl)-1,3,5-triazine ...