Self-assembly of a M4L6 complex with unexpected S4 symmetry
Giri, C., Topic, F., Mal, P., & Rissanen, K. (2014). Self-assembly of a M4L6 complex with unexpected S4 symmetry. Dalton transactions, 43(48), 17889-17892. https://doi.org/10.1039/C4DT02754J
Published in
Dalton transactionsDate
2014Copyright
© The Royal Society of Chemistry 2014. This is a final draft version of an article whose final and definitive form has been published by RSC. Published in this repository with the kind permission of the publisher.
Using 1,4-diaminobenzene and 2-formylpyridine as simple
building blocks results in a 1D ligand (rod, L2) to 2D (M4L4
grid, C1) to 3D (S4
symmetrical M4L6, C2) complexes upon
sequential addition of Cu(I) and Fe(II) ions. The complex C2
can be seen as the smallest possible pseudo-tetrahedron with
S4
symmetry.
Publisher
R S C PublicationsISSN Search the Publication Forum
1477-9226Publication in research information system
https://converis.jyu.fi/converis/portal/detail/Publication/23983822
Metadata
Show full item recordCollections
Related items
Showing items with similar title or keywords.
-
Synthesis, X-ray Crystal Structure and Antimicrobial Activity of Unexpected Trinuclear Cu(II) Complex from s-Triazine-Based Di-Compartmental Ligand via Self-Assembly
Soliman, M. Saied; Lasri, Jamal; Haukka, Matti; Sholkamy, N. Essam; Al-Rasheed, H. Hessa; El-Faham, Ayman (MDPI, 2019)The synthesis and X-ray crystal structure of the trinuclear [Cu3(HL)(Cl)2(NO3)(H2O)5](NO3)2 complex of the s-triazine-based di-compartmental ligand, 2-methoxy-4,6-bis(2-(pyridin-2-ylmsethylene)hydrazinyl)-1,3,5-triazine ... -
Oxidative DNA cleavage mediated by a new unexpected [Pd(BAPP)][PdCl4] complex (BAPP = 1,4-bis(3-aminopropyl)piperazine) : crystal structure, DNA binding and cytotoxic behavior
Ragab, Mona S.; Shehata, Mohamed R.; Shoukry, Mohamed M.; Haukka, Matti; Ragheb, Mohamed A. (Royal Society of Chemistry (RSC), 2022)A novel Pd(II) double complex, [Pd(BAPP)][PdCl4], containing the 1,4-bis(3-aminopropyl)piperazine (BAPP) ligand is investigated. X-ray crystallography of a single crystal confirmed the structure of the [Pd(BAPP)][PdCl4] ... -
Applications of DNA self-assembled structures in nanoelectronics and plasmonics
Shen, Boxuan (University of Jyväskylä, 2018)In this thesis, the potential applications of DNA self-assembled structures were explored in both nanoelectronics and plasmonics. The works can be divided into two parts: electrical characterization of unmodified multilayered ... -
Subcomponent self‐assembly of a cyclic tetranuclear Fe(II) helicate in a highly diastereoselective self‐sorting manner
Anhäuser, Jana; Puttreddy, Rakesh; Glanz, Lukas; Schneider, Andreas; Engeser, Marianne; Rissanen, Kari; Lützen, Arne (Wiley-VCH Verlag, 2019)An enantiomerically pure diamine based on the 4,15‐difunctionalized [2.2]paracyclophane scaffold and 2‐formylpyridine self‐assemble into an optically pure cyclic metallosupramolecular Fe₄L₆ helicate upon mixing with iron(II) ... -
Tertiary Chiral Nanostructures from C‐H∙∙∙F Directed Assembly of Chiroptical Superatoms
Shen, Hui; Xu, Zhen; Wang, Lingzheng; Han, Ying-Zi; Liu, Xianhu; Malola, Sami; Teo, Boon K.; Häkkinen, Hannu; Zheng, Nanfeng (Wiley, 2021)Chiral hierarchical structures are universal in nature, whereas quite challenging to mimic in man-made synthesis. We report herein the synthesis and structure of tertiary chiral nanostructures with 100% optical purity. A ...