dc.contributor.author | Schachner, Jörg A. | |
dc.contributor.author | Mösch-Zanetti, Nadia C. | |
dc.contributor.author | Peuronen, Anssi | |
dc.contributor.author | Lehtonen, Ari | |
dc.date.accessioned | 2017-07-05T06:11:21Z | |
dc.date.available | 2019-06-16T21:35:45Z | |
dc.date.issued | 2017 | |
dc.identifier.citation | Schachner, J. A., Mösch-Zanetti, N. C., Peuronen, A., & Lehtonen, A. (2017). Dioxidomolybdenum(VI) and -tungsten(VI) complexes with tetradentate amino bisphenolates as catalysts for epoxidation. <i>Polyhedron</i>, <i>134</i>, 73-78. <a href="https://doi.org/10.1016/j.poly.2017.06.011" target="_blank">https://doi.org/10.1016/j.poly.2017.06.011</a> | |
dc.identifier.other | CONVID_27072294 | |
dc.identifier.other | TUTKAID_74172 | |
dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/54850 | |
dc.description.abstract | Sixteen molybdenum and tungsten complexes with tripodal or linear tetradentate amino bisphenol ligands were studied as catalysts for the epoxidation of cis-cyclooctene, 1-octene, styrene, limonene and α-terpineol. These complexes can be divided into different categories upon key features, i.e. central metal (Mo versus W), side-arm donor (O versus N), hybridization of the N-donor (pyridine versus amine), ligand geometry (tripodal versus linear diamine) and sterical hindrance (Me versus tert-Bu substituents in the phenol part). All complexes can catalyse selectively the epoxidation of cis-cyclooctene by tert-butylhydroperoxide whereas the activities and selectivities towards other olefins (1-octene, styrene, limonene and α-terpineol) show large differences. When H2O2 was used as an oxidant in the epoxidation of cis-cyclooctene, only two of eight Mo complexes and four of eight W complexes showed any activity. This study revealed no clear correlations between the Mo and W catalyst structures and their activities. | |
dc.language.iso | eng | |
dc.publisher | Elsevier Ltd. | |
dc.relation.ispartofseries | Polyhedron | |
dc.subject.other | chemistry | |
dc.subject.other | amino acids | |
dc.subject.other | styrene | |
dc.subject.other | hydrocarbons | |
dc.subject.other | catalysts | |
dc.title | Dioxidomolybdenum(VI) and -tungsten(VI) complexes with tetradentate amino bisphenolates as catalysts for epoxidation | |
dc.type | article | |
dc.identifier.urn | URN:NBN:fi:jyu-201707033218 | |
dc.contributor.laitos | Kemian laitos | fi |
dc.contributor.laitos | Department of Chemistry | en |
dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
dc.date.updated | 2017-07-03T12:15:09Z | |
dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
dc.description.reviewstatus | peerReviewed | |
dc.format.pagerange | 73-78 | |
dc.relation.issn | 0277-5387 | |
dc.relation.numberinseries | 0 | |
dc.relation.volume | 134 | |
dc.type.version | acceptedVersion | |
dc.rights.copyright | © 2017 Elsevier Ltd. This is a final draft version of an article whose final and definitive form has been published by Elsevier. Published in this repository with the kind permission of the publisher. | |
dc.rights.accesslevel | openAccess | fi |
dc.subject.yso | kemia | |
dc.subject.yso | aminohapot | |
dc.subject.yso | styreeni | |
dc.subject.yso | hiilivedyt | |
dc.subject.yso | katalyytit | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p1801 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p9530 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p9496 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p1169 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p15480 | |
dc.relation.doi | 10.1016/j.poly.2017.06.011 | |
dc.type.okm | A1 | |