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From Mannose to Small Amphiphilic Polyol: Perfect Linearity Leads To Spontaneous Aggregation

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Saloranta, T., Peuronen, A., Dieterich, J. M., Ruokolainen, J., Lahtinen, M., & Leino, R. (2016). From Mannose to Small Amphiphilic Polyol: Perfect Linearity Leads To Spontaneous Aggregation. Crystal Growth and Design, 16 (2), 655-661. doi:10.1021/acs.cgd.5b01135
Published in
Crystal Growth and Design
Authors
Saloranta, Tiina |
Peuronen, Anssi |
Dieterich, Johannes M. |
Ruokolainen, Janne |
Lahtinen, Manu |
Leino, Reko
Date
2016
Discipline
Epäorgaaninen ja analyyttinen kemia
Copyright
© 2015 American Chemical Society. This is a final draft version of an article whose final and definitive form has been published by American Chemical Society. Published in this repository with the kind permission of the publisher.

 
Terminally unsaturated and diastereochemically pure polyol derived from d-mannose shows spontaneous aggregation behavior in water solution. In order to study and clarify this unforeseen phenomenon, a conformational study based on NMR spectroscopy combined with ab initio structure analysis using the COSMO-solvation model was pursued. The results, together with X-ray diffraction studies, suggest a low energy linear conformation for this particular substrate both in solid states and in solution. For such small-sized acyclic carbohydrate derivatives, the linear conformation appears to be a key prerequisite for the unusual molecular self-assembly reported herein.
Publisher
American Chemical Society
ISSN Search the Publication Forum
1528-7483
Keywords
d-mannose polyols spontaneous aggregation
DOI
10.1021/acs.cgd.5b01135
URI

http://urn.fi/URN:NBN:fi:jyu-201704121980

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