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dc.contributor.authorSaloranta, Tiina
dc.contributor.authorPeuronen, Anssi
dc.contributor.authorDieterich, Johannes M.
dc.contributor.authorRuokolainen, Janne
dc.contributor.authorLahtinen, Manu
dc.contributor.authorLeino, Reko
dc.date.accessioned2017-04-19T07:16:50Z
dc.date.available2017-04-19T07:16:50Z
dc.date.issued2016
dc.identifier.citationSaloranta, T., Peuronen, A., Dieterich, J. M., Ruokolainen, J., Lahtinen, M., & Leino, R. (2016). From Mannose to Small Amphiphilic Polyol: Perfect Linearity Leads To Spontaneous Aggregation. <em>Crystal Growth and Design</em>, 16 (2), 655-661. <a href="https://doi.org/10.1021/acs.cgd.5b01135">doi:10.1021/acs.cgd.5b01135</a>
dc.identifier.otherTUTKAID_69365
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/53620
dc.description.abstractTerminally unsaturated and diastereochemically pure polyol derived from d-mannose shows spontaneous aggregation behavior in water solution. In order to study and clarify this unforeseen phenomenon, a conformational study based on NMR spectroscopy combined with ab initio structure analysis using the COSMO-solvation model was pursued. The results, together with X-ray diffraction studies, suggest a low energy linear conformation for this particular substrate both in solid states and in solution. For such small-sized acyclic carbohydrate derivatives, the linear conformation appears to be a key prerequisite for the unusual molecular self-assembly reported herein.
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.relation.ispartofseriesCrystal Growth and Design
dc.subject.otherd-mannose
dc.subject.otherpolyols
dc.subject.otherspontaneous aggregation
dc.titleFrom Mannose to Small Amphiphilic Polyol: Perfect Linearity Leads To Spontaneous Aggregation
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201704121980
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemia
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2017-04-12T12:15:03Z
dc.type.coarjournal article
dc.description.reviewstatuspeerReviewed
dc.format.pagerange655-661
dc.relation.issn1528-7483
dc.relation.volume16
dc.type.versionacceptedVersion
dc.rights.copyright© 2015 American Chemical Society. This is a final draft version of an article whose final and definitive form has been published by American Chemical Society. Published in this repository with the kind permission of the publisher.
dc.rights.accesslevelopenAccessfi
dc.relation.doi10.1021/acs.cgd.5b01135


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