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Systematic Construction of Ternary Cocrystals by Orthogonal and Robust Hydrogen and Halogen Bonds

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Topic, F., & Rissanen, K. (2016). Systematic Construction of Ternary Cocrystals by Orthogonal and Robust Hydrogen and Halogen Bonds. Journal of the American Chemical Society, 138(20), 6610-6616. https://doi.org/10.1021/jacs.6b02854
Published in
Journal of the American Chemical Society
Authors
Topic, Filip |
Rissanen, Kari
Date
2016
Discipline
Orgaaninen kemiaOrganic Chemistry
Copyright
© 2016 American Chemical Society. This is a final draft version of an article whose final and definitive form has been published by American Chemical Society. Published in this repository with the kind permission of the publisher.

 
A carefully designed strategy is presented for the construction of ternary cocrystals, based on the orthogonality of two supramolecular interaction modes: hydrogen bonding between crown ethers and thioureas and the halogen bonding between thioureas and perfluorohalocarbons. Tested on a set comprising two crown ethers, two thioureas and five halogen bond donors, the strategy resulted in a high, 75% success rate, with 15/20 component combinations yielding at least one cocrystal. Crystal structure analysis revealed the interplay between the hydrogen and halogen bonding motifs, also shedding light on the variables affecting their formation.
Publisher
American Chemical Society
ISSN Search the Publication Forum
0002-7863
Keywords
ternary cocrystals halogen bonds vety kemia
DOI
https://doi.org/10.1021/jacs.6b02854
URI

http://urn.fi/URN:NBN:fi:jyu-201704121987

Publication in research information system

https://converis.jyu.fi/converis/portal/detail/Publication/26041504

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