Cocrystal trimorphism as a consequence of the orthogonality of halogen- and hydrogen-bonds synthons
Topić, F., Lisac, K., Arhangelskis, M., Rissanen, K., Cinčić, D., & Friščić, T. (2019). Cocrystal trimorphism as a consequence of the orthogonality of halogen- and hydrogen-bonds synthons. Chemical Communications, 55(93), 14066-14069. https://doi.org/10.1039/C9CC06735C
Published inChemical Communications
© The Royal Society of Chemistry 2019
True trimorphic cocrystals, i.e. multi-component molecular crystals of identical composition that exhibit three polymorphic structures, are exceedingly rare and so far no halogen-bonded cocrystal system has been reported to exhibit trimorphism. Here we describe a unique example of a trimorphic cocrystal exhibiting both hydrogen and halogen bonds in which the differences between polymorphs reveal their orthogonality, evident by the apparently independent variation of well-defined hydrogen- and halogen-bonded motifs.
PublisherRoyal Society of Chemistry
ISSN Search the Publication Forum1359-7345
Publication in research information system
MetadataShow full item record
Additional information about fundingWe thank the support of the Government of Canada Banting Fellowship (FT), University of Jyväskylä, NSERC Discovery Grant (RGPIN-2017-06467), E. W. R. Steacie Memorial Fellowship (SMFSU 507347-17), McGill University Herchel Smith Scholarship, Croatian Science Foundation (IP-2014-09-7367).
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