| dc.contributor.author | Hänninen, Mikko M. | |
| dc.contributor.author | Pal, Kuntal | |
| dc.contributor.author | Day, Benjamin M. | |
| dc.contributor.author | Pugh, Thomas | |
| dc.contributor.author | Layfield, Richard A. | |
| dc.date.accessioned | 2017-04-12T09:18:24Z | |
| dc.date.available | 2017-06-27T21:45:08Z | |
| dc.date.issued | 2016 | |
| dc.identifier.citation | Hänninen, M. M., Pal, K., Day, B. M., Pugh, T., & Layfield, R. A. (2016). A three-coordinate iron–silylene complex stabilized by ligand–ligand dispersion forces. <i>Dalton Transactions</i>, <i>45</i>(28), 11301-11305. <a href="https://doi.org/10.1039/C6DT02486F" target="_blank">https://doi.org/10.1039/C6DT02486F</a> | |
| dc.identifier.other | CONVID_26098574 | |
| dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/53583 | |
| dc.description.abstract | The structural and bonding properties of a three-coordinate N-heterocyclic silyene (NHSi) complex of the iron(II) amide [Fe{N(SiMe3)2}2] are reported. Computational studies reveal that dispersion forces between the amido SiMe3 substituents and the isopropyl substituents on the NHSi ligand significantly enhance the stability of the complex, along with Fe-to-Si π-backbonding. | en |
| dc.language | eng | |
| dc.language.iso | eng | |
| dc.publisher | RSC Publications | |
| dc.relation.ispartofseries | Dalton Transactions | |
| dc.subject.other | bonding | |
| dc.subject.other | heterocyclic silyene complexes | |
| dc.title | A three-coordinate iron–silylene complex stabilized by ligand–ligand dispersion forces | |
| dc.type | research article | |
| dc.identifier.urn | URN:NBN:fi:jyu-201704121976 | |
| dc.contributor.laitos | Kemian laitos | fi |
| dc.contributor.laitos | Department of Chemistry | en |
| dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
| dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
| dc.date.updated | 2017-04-12T09:15:03Z | |
| dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
| dc.description.reviewstatus | peerReviewed | |
| dc.format.pagerange | 11301-11305 | |
| dc.relation.issn | 1477-9226 | |
| dc.relation.numberinseries | 28 | |
| dc.relation.volume | 45 | |
| dc.type.version | acceptedVersion | |
| dc.rights.copyright | © The Royal Society of Chemistry 2016. This is a final draft version of an article whose final and definitive form has been published by Royal Society if Chemistry. Published in this repository with the kind permission of the publisher. | |
| dc.rights.accesslevel | openAccess | fi |
| dc.type.publication | article | |
| dc.relation.grantnumber | 274505 | |
| dc.subject.yso | kompleksiyhdisteet | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p30190 | |
| dc.relation.doi | 10.1039/C6DT02486F | |
| dc.relation.funder | Suomen Akatemia | fi |
| dc.relation.funder | Research Council of Finland | en |
| jyx.fundingprogram | Tutkijatohtori, SA | fi |
| jyx.fundingprogram | Postdoctoral Researcher, AoF | en |
| jyx.fundinginformation | The authors thank The Academy of Finland (Research Fellowship 274505 to MM) and the EPSRC (EP/K039547/1) for funding. | |
| dc.type.okm | A1 | |
