Show simple item record

dc.contributor.authorHänninen, Mikko M.
dc.contributor.authorPal, Kuntal
dc.contributor.authorDay, Benjamin M.
dc.contributor.authorPugh, Thomas
dc.contributor.authorLayfield, Richard A.
dc.date.accessioned2017-04-12T09:18:24Z
dc.date.available2017-06-27T21:45:08Z
dc.date.issued2016
dc.identifier.citationHänninen, Mikko M.; Pal, Kuntal; Day, Benjamin M.; Pugh, Thomas; Layfield, Richard A. (2016). A three-coordinate iron–silylene complex stabilized by ligand–ligand dispersion forces. Dalton Transactions, 45 (28), 11301-11305. DOI: 10.1039/C6DT02486F
dc.identifier.otherCONVID_26098574
dc.identifier.otherTUTKAID_70540
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/53583
dc.description.abstractThe structural and bonding properties of a three-coordinate N-heterocyclic silyene (NHSi) complex of the iron(II) amide [Fe{N(SiMe3)2}2] are reported. Computational studies reveal that dispersion forces between the amido SiMe3 substituents and the isopropyl substituents on the NHSi ligand significantly enhance the stability of the complex, along with Fe-to-Si π-backbonding.en
dc.languageeng
dc.language.isoeng
dc.publisherRSC Publications
dc.relation.ispartofseriesDalton Transactions
dc.subject.otherbonding
dc.subject.otherheterocyclic silyene complexes
dc.titleA three-coordinate iron–silylene complex stabilized by ligand–ligand dispersion forces
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201704121976
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2017-04-12T09:15:03Z
dc.type.coarjournal article
dc.description.reviewstatuspeerReviewed
dc.format.pagerange11301-11305
dc.relation.issn1477-9226
dc.relation.numberinseries28
dc.relation.volume45
dc.type.versionacceptedVersion
dc.rights.copyright© The Royal Society of Chemistry 2016. This is a final draft version of an article whose final and definitive form has been published by Royal Society if Chemistry. Published in this repository with the kind permission of the publisher.
dc.rights.accesslevelopenAccessfi
dc.relation.grantnumber274505
dc.subject.ysokompleksiyhdisteet
jyx.subject.urihttp://www.yso.fi/onto/yso/p30190
dc.relation.doi10.1039/C6DT02486F
dc.relation.funderSuomen Akatemiafi
dc.relation.funderAcademy of Finlanden
jyx.fundingprogramTutkijatohtori, SAfi
jyx.fundingprogramPostdoctoral Researcher, AoFen
jyx.fundinginformationThe authors thank The Academy of Finland (Research Fellowship 274505 to MM) and the EPSRC (EP/K039547/1) for funding.


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record