Metallogel formation in aqueous DMSO by perfluoroalkyl decorated terpyridine ligands
Tatikonda, R., Bhowmik, S., Rissanen, K., Haukka, M., & Cametti, M. (2016). Metallogel formation in aqueous DMSO by perfluoroalkyl decorated terpyridine ligands. Dalton Transactions, 45(32), 12756-12762. https://doi.org/10.1039/c6dt02008a
Published in
Dalton TransactionsDate
2016Discipline
Epäorgaaninen ja analyyttinen kemiaOrgaaninen kemiaSoveltava kemiaInorganic and Analytical ChemistryOrganic ChemistryApplied ChemistryCopyright
© 2016 The Royal Society of Chemistry. This is a final draft version of a paper whose final and definitive version is published by RSC Publications. Published in this repository with the kind permission of the publisher.
Terpyridine based ligands 1 and 2, decorated with a C8F17 perfluorinated tag, are able to form stable thermoreversible gels in the presence of several d-block metal chloride salts. The gel systems obtained have been characterized by NMR, X-ray diffraction, electron microscopies and Tgel experiments in order to gain insights into the observed different behaviour of the two similar ligands, also in terms of the effect of additional common anionic species.
Publisher
RSC PublicationsISSN Search the Publication Forum
1477-9226Publication in research information system
https://converis.jyu.fi/converis/portal/detail/Publication/26134290
Metadata
Show full item recordCollections
Related items
Showing items with similar title or keywords.
-
Bipyridine based metallogels : an unprecedented difference in photochemical and chemical reduction in the in situ nanoparticle formation
Tatikonda, Rajendhraprasad; Bertula, Kia; Nonappa; Hietala, Sami; Rissanen, Kari; Haukka, Matti (Royal Society of Chemistry, 2017)Metal co-ordination induced supramolecular gelation of low molecular weight organic ligands is a rapidly expanding area of research due to the potential in creating hierarchically self-assembled multi-stimuli responsive ... -
Transition metal ion induced hydrogelation by amino-terpyridine ligands
Bhowmik, Sandip; Ghosh, Biswa Nath; Rissanen, Kari (RSC Publications, 2014)Hydrogelation behavior of two amino-terpyridine ligands in the presence of divalent metal ions in water was studied in detail. The effect of ligand structure and different counter anions on the gel morphologies was also explored. -
Synthesis and structural characterization of new transition metal complexes of a highly luminescent amino-terpyridine ligand
Nath Ghosh, Biswa; Puttreddy, Rakesh; Rissanen, Kari (Elsevier Ltd, 2020)The synthesis, NMR and UV-Vis spectroscopy measurements and X-ray diffraction analysis of four new metal complexes of the amino terpyridine ligand 4́-[4-(4-aminophenyl)phenyl]-2,2́:6́,2́́-terpyridine L, namely [FeL2](ClO4)2 ... -
Ruthenium(II) carbonyl compounds with the 4′-chloro-2,2′:6′,2′′-terpyridine ligand
Tatikonda, Rajendhraprasad; Haukka, Matti (International Union of Crystallography, 2017)Two ruthenium carbonyl complexes with the 4′-chloro-2,2′:6′,2′′-terpyridine ligand (tpy-Cl, C15H10ClN3), i.e. [RuCl(tpy-Cl)(CO)2][RuCl3(CO)3] (I) [systematic name: cis-dicarbonylchlorido(4′-chloro-2,2′:6′,2′′-terpyridi ... -
Alkyl-Substituted Aminobis(phosphonates) : Efficient Precipitating Agents for Rare Earth Elements, Thorium, and Uranium in Aqueous Solutions
Virtanen, Emilia J.; Perämäki, Siiri; Helttunen, Kaisa; Väisänen, Ari; Moilanen, Jani O. (American Chemical Society (ACS), 2021)The efficient and environmentally sustainable separation process for rare earth elements (REE), especially for adjacent lanthanoids, remains a challenge due to the chemical similarity of REEs. Tetravalent actinoids, thorium, ...