Metallogel formation in aqueous DMSO by perfluoroalkyl decorated terpyridine ligands
Tatikonda, R., Bhowmik, S., Rissanen, K., Haukka, M., & Cametti, M. (2016). Metallogel formation in aqueous DMSO by perfluoroalkyl decorated terpyridine ligands. Dalton Transactions, 45(32), 12756-12762. https://doi.org/10.1039/c6dt02008a
Published inDalton Transactions
DisciplineEpäorgaaninen ja analyyttinen kemiaOrgaaninen kemiaSoveltava kemiaInorganic and Analytical ChemistryOrganic ChemistryApplied Chemistry
© 2016 The Royal Society of Chemistry. This is a final draft version of a paper whose final and definitive version is published by RSC Publications. Published in this repository with the kind permission of the publisher.
Terpyridine based ligands 1 and 2, decorated with a C8F17 perfluorinated tag, are able to form stable thermoreversible gels in the presence of several d-block metal chloride salts. The gel systems obtained have been characterized by NMR, X-ray diffraction, electron microscopies and Tgel experiments in order to gain insights into the observed different behaviour of the two similar ligands, also in terms of the effect of additional common anionic species.
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