University of Jyväskylä | JYX Digital Repository

  • English  | Give feedback |
    • suomi
    • English
 
  • Login
JavaScript is disabled for your browser. Some features of this site may not work without it.
View Item 
  • JYX
  • Artikkelit
  • Matemaattis-luonnontieteellinen tiedekunta
  • View Item
JYX > Artikkelit > Matemaattis-luonnontieteellinen tiedekunta > View Item

Metallophilic interactions in polymeric group 11 thiols

ThumbnailFinal Draft
View/Open
1.5 Mb

Downloads:  
Show download detailsHide download details  
Kolari, K., Sahamies, J., Kalenius, E., Novikov, A. S., Kukushkin, V. Y., & Haukka, M. (2016). Metallophilic interactions in polymeric group 11 thiols. Solid State Sciences, 60(October), 92-98. https://doi.org/10.1016/j.solidstatesciences.2016.08.005
Published in
Solid State Sciences
Authors
Kolari, Kalle |
Sahamies, Joona |
Kalenius, Elina |
Novikov, Alexander S. |
Kukushkin, Vadim Yu |
Haukka, Matti
Date
2016
Discipline
Epäorgaaninen ja analyyttinen kemiaOrgaaninen kemiaInorganic and Analytical ChemistryOrganic Chemistry
Copyright
© 2016 Elsevier Masson SAS. This is a final draft version of an article whose final and definitive form has been published by Elsevier. Published in this repository with the kind permission of the publisher.

 
Three polymeric group 11 transition metal polymers featuring metallophilic interactions were obtained directly via self-assembly of metal ions and 4-pyridinethiol ligands. In the cationic [Cu2(S-pyH)4]n2+ with [ZnCl4]n2− counterion (1) and in the neutral [Ag(S-py) (S-pyH)]n (2) 4-pyridinethiol (S-pyH) and its deprotonated form (S-py) are coordinated through the sulfur atom. Both ligands are acting as bridging ligands linking the metal centers together. In the solid state, the gold(I) polymer [Au(S-pyH)2]Cl (3) consists of the repeating cationic [Au(S-pyH)2]+ units held together by aurophilic interactions. Compound 1 is a zig-zag chain, whereas the metal chains in the structures of 2 and 3 are linear. The protonation level of the thiol ligand had an impact on the crystallization of polymers. Both nature of the metal center and reaction conditions affected the polymerization. QTAIM analysis confirmed direct metal-metal contacts only in polymers 1 and 3. In polymer 2, no theoretical evidence of argentophilic contacts was obtained even though the Ag⋅⋅⋅Ag distance was found to be less than sum of the Bondi's van der Waals radius of silver. ...
Publisher
Elsevier BV
ISSN Search the Publication Forum
1293-2558
Keywords
Cu Ag Au 4-pyridinethiol metallophilic interactions
DOI
https://doi.org/10.1016/j.solidstatesciences.2016.08.005
URI

http://urn.fi/URN:NBN:fi:jyu-201608303907

Publication in research information system

https://converis.jyu.fi/converis/portal/detail/Publication/26162481

Metadata
Show full item record
Collections
  • Matemaattis-luonnontieteellinen tiedekunta [4954]
Related funder(s)
Academy of Finland
Funding program(s)
Academy Research Fellow, AoF; Research costs of Academy Research Fellow, AoF
Additional information about funding
Financial support provided by the Magnus Ehrnrooth foundation (K.M) and Academy of Finland (M.H project no 139571, E.K project no's 284562 and 278743) as well as COST Action CM1302 are gratefully acknowledged. A.S.N is grateful to Russian Foundation for Basic Research for support (project No. 16-33-60063).

Related items

Showing items with similar title or keywords.

  • Homo- and heterometallic metal atomic strings 

    Sahamies, Joona (2016)
    Pro gradu -tutkielmani keskittyy metallofiiliseen vuorovaikutukseen ylipäätänsä ja etenkin metallofiiliseen vuorovaikutukseen metalliatomiketjuissa. Metallopolymeerien ja niiden erään alaluokan, laajennettujen metalliatomiketjujen ...
  • Self-assembly of square planar rhodium carbonyl complexes with 4,4-disubstituted-2,2’-bipyridine ligands 

    Kolari, Kalle; Laurila, Elina; Chernysheva, Maria; Hirva, Pipsa; Haukka, Matti (Elsevier, 2020)
    The impact of non-covalent interactions and reaction conditions on formation and self-assembly of ionic pairs of Rh complexes with 4,4’-disubstituted bipyridine ligands ([Rh(L1)(CO)2][Rh(CO)2Cl2])n (1), [Rh(L1)2Cl2][Rh(CO)2Cl2] ...
  • From isolated 1H-pyrazole cryptand anion receptors to hybrid inorganic–organic 1D helical polymeric anion receptors 

    Pitarch-Jarque, Javier; Belda, Raquel; García-España, Laura; Llinares, José M.; Pan, Fangfang; Rissanen, Kari; Navarro, Pilar; García-España, Enrique (R S C Publications, 2015)
    We report on a novel 1-D helical coordination polymer formed by protonated polyamine 1H-pyrazole cryptands interconnected by Cu2+ metal ions able to encapsulate anionic species behaving as a multianion receptor. Switching ...
  • Selective Laser Sintering of Metal-Organic Frameworks : Production of Highly Porous Filters by 3D Printing onto a Polymeric Matrix 

    Lahtinen, Elmeri; Precker, Rafaella; Lahtinen, Manu; Hey-Hawkins, Evamarie; Haukka, Matti (Wiley - VCH Verlag GmbH & Co. KGaA, 2019)
    Metal‐organic frameworks (MOFs) have raised a lot of interest, especially as adsorbing materials, because of their unique and well‐defined pore structures. One of the main challenges in the utilization of MOFs is their ...
  • Hallinnollinen vuorovaikutus sairaalatyöyhteisössä 

    Pennanen, Eveliina (University of Jyväskylä, 2018)
    As the healthcare sector is constantly growing and changing, it is more important than ever to consider how we can ensure that a sufficient number of employees are available in healthcare organizations now and in the ...
  • Browse materials
  • Browse materials
  • Articles
  • Conferences and seminars
  • Electronic books
  • Historical maps
  • Journals
  • Tunes and musical notes
  • Photographs
  • Presentations and posters
  • Publication series
  • Research reports
  • Research data
  • Study materials
  • Theses

Browse

All of JYXCollection listBy Issue DateAuthorsSubjectsPublished inDepartmentDiscipline

My Account

Login

Statistics

View Usage Statistics
  • How to publish in JYX?
  • Self-archiving
  • Publish Your Thesis Online
  • Publishing Your Dissertation
  • Publication services

Open Science at the JYU
 
Data Protection Description

Accessibility Statement

Unless otherwise specified, publicly available JYX metadata (excluding abstracts) may be freely reused under the CC0 waiver.
Open Science Centre