A coumarin based gold(I)-alkynyl complex: a new class of supramolecular hydrogelators
| dc.contributor.author | Moro, Artur J. | |
| dc.contributor.author | Rome, Bertrand | |
| dc.contributor.author | Aguiló, Elisabet | |
| dc.contributor.author | Arcau, Julià | |
| dc.contributor.author | Puttreddy, Rakesh | |
| dc.contributor.author | Rissanen, Kari | |
| dc.contributor.author | Lima, João Carlos | |
| dc.contributor.author | Rodríguez, Laura | |
| dc.date.accessioned | 2016-07-01T06:06:17Z | |
| dc.date.available | 2016-07-01T06:06:17Z | |
| dc.date.issued | 2015 | |
| dc.identifier.citation | Moro, A. J., Rome, B., Aguiló, E., Arcau, J., Puttreddy, R., Rissanen, K., Lima, J. C., & Rodríguez, L. (2015). A coumarin based gold(I)-alkynyl complex: a new class of supramolecular hydrogelators. <i>Organic and biomolecular chemistry</i>, <i>13</i>(7), 2026-2033. <a href="https://doi.org/10.1039/C4OB02077D" target="_blank">https://doi.org/10.1039/C4OB02077D</a> | |
| dc.identifier.other | CONVID_24534726 | |
| dc.identifier.other | TUTKAID_65144 | |
| dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/50670 | |
| dc.description.abstract | A phosphine-gold(I)-alkynyl-coumarin complex, [Au{7-(prop-2-ine-1-yloxy)-1-benzopyran-2-one}- (DAPTA)] (1), was synthesized and the formation of long luminescent fibers in solution was characterized via fluorescence microscopy and dynamic light scattering. The fibers presented strong blue and green luminescence, suggesting that the gold(I) in the complex increased intersystem crossing due to the heavy atom effect, resulting in a significant increase in triplet emission. The X-ray structure of the fibers indicates that both aurophilic, π–π interactions and hydrogen bonding contribute to their formation in aqueous solvents. | |
| dc.language.iso | eng | |
| dc.publisher | RSC Publications | |
| dc.relation.ispartofseries | Organic and biomolecular chemistry | |
| dc.subject.other | coumarin based | |
| dc.subject.other | gold(I)-alkynyl complex | |
| dc.subject.other | supramolecular | |
| dc.subject.other | hydrogelators | |
| dc.title | A coumarin based gold(I)-alkynyl complex: a new class of supramolecular hydrogelators | |
| dc.type | article | |
| dc.identifier.urn | URN:NBN:fi:jyu-201606303416 | |
| dc.contributor.laitos | Kemian laitos | fi |
| dc.contributor.laitos | Department of Chemistry | en |
| dc.contributor.oppiaine | Orgaaninen kemia | fi |
| dc.contributor.oppiaine | Nanoscience Center | fi |
| dc.contributor.oppiaine | Organic Chemistry | en |
| dc.contributor.oppiaine | Nanoscience Center | en |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
| dc.date.updated | 2016-06-30T12:15:31Z | |
| dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
| dc.description.reviewstatus | peerReviewed | |
| dc.format.pagerange | 2026-2033 | |
| dc.relation.issn | 1477-0520 | |
| dc.relation.numberinseries | 7 | |
| dc.relation.volume | 13 | |
| dc.type.version | publishedVersion | |
| dc.rights.copyright | © the Authors, 2015. The journal is © The Royal Society of Chemistry 2015. This is an open access article distributed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. | |
| dc.rights.accesslevel | openAccess | fi |
| dc.rights.url | https://creativecommons.org/licenses/by-nc/3.0/ | |
| dc.relation.doi | 10.1039/C4OB02077D | |
| dc.type.okm | A1 |
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Ellei muuten mainita, aineiston lisenssi on © the Authors, 2015. The journal is © The Royal Society of Chemistry 2015. This is an open access article distributed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.