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dc.contributor.authorGiese, Michael
dc.contributor.authorAlbrecht, Markus
dc.contributor.authorValkonen, Arto
dc.contributor.authorRissanen, Kari
dc.date.accessioned2016-03-16T08:24:21Z
dc.date.available2016-03-16T08:24:21Z
dc.date.issued2015
dc.identifier.citationGiese, M., Albrecht, M., Valkonen, A., & Rissanen, K. (2015). The pentafluorophenyl group as π-acceptor for anions : a case study. <em>Chemical Science</em>, 6 (1), 354-359. <a href="http://dx.doi.org/10.1039/C4SC02762K">doi:10.1039/C4SC02762K</a>
dc.identifier.otherTUTKAID_64444
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/49068
dc.description.abstractThe present study gives a comprehensive insight into anion–p interactions in the solid state, focusing on purely organic and charge-neutral fluorophenyl groups bearing a positive charge located at a side chain. The detailed statistical analysis of a series of structural data sets shows the geometrical variability of anion–p bonding in the solid state. It reveals the directing substituents at the arene as key elements for the positional preferences of anions above p-systems. The structural variety of the interaction between anions and electron-deficient arenes is considered by use of the hapticity concept. Together with new evaluation criteria, two helpful tools to understand and describe anion–p interactions in the solid are used.
dc.language.isoeng
dc.publisherRSC Publications
dc.relation.ispartofseriesChemical Science
dc.subject.otherelectron-deficient
dc.subject.otherevaluation criteria
dc.subject.otherhapticities
dc.subject.otherkey elements
dc.subject.otherpentafluorophenyl
dc.subject.otherpositive charges
dc.subject.otherside-chains
dc.subject.otherstructural data
dc.titleThe pentafluorophenyl group as π-acceptor for anions : a case study
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201603151848
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineOrgaaninen kemia
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2016-03-15T13:15:03Z
dc.type.coarjournal article
dc.description.reviewstatuspeerReviewed
dc.format.pagerange354-359
dc.relation.issn2041-6520
dc.relation.volume6
dc.type.versionpublishedVersion
dc.rights.copyright© the Authors 2015. This is an open access article licensed under a Creative Commons Attribution 3.0 Unported Licence.
dc.rights.accesslevelopenAccessfi
dc.rights.urlhttp://creativecommons.org/licenses/by/3.0/
dc.relation.doi10.1039/C4SC02762K


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© the Authors 2015. This is an open access article licensed under a Creative Commons Attribution 3.0 Unported Licence.
Except where otherwise noted, this item's license is described as © the Authors 2015. This is an open access article licensed under a Creative Commons Attribution 3.0 Unported Licence.