Electron-deficient trifluoromethyl-substituted sub-components affect the properties of M4L4 tetrahedral cages
Struch, N., Topic, F., Rissanen, K., & Lützen, A. (2017). Electron-deficient trifluoromethyl-substituted sub-components affect the properties of M4L4 tetrahedral cages. Dalton Transactions, 46(33), 10809-10813. https://doi.org/10.1039/C7DT02182H
Published inDalton Transactions
© The Royal Society of Chemistry 2017. This is a final draft version of an article whose final and definitive form has been published by RSC. Published in this repository with the kind permission of the publisher.
Two supramolecular tetrahedral cages based on a new electron-deficient trifluoromethyl-substituted pyridylimine ligand are synthesised by sub-component self-assembly. Their structures are characterised by NMR und UV-Vis spectroscopy, high-resolution mass spectrometry and single crystal X-ray diffraction. The iron(II) complex shows host–guest chemistry, complex-to-complex transformations and novel electronic properties.
PublisherRoyal Society of Chemistry
Publication in research information system
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Related funder(s)Academy of Finland
Funding program(s)Research post as Academy Professor, AoF; Research costs of Academy Professor, AoF
Additional information about fundingFinancial support from DFG (SFB 813 – Chemistry at Spin Centers) and the Academy of Finland (K. R.: project no's. 263256, 292746 and 265328) is gratefully acknowledged. N. S. thanks Evonik Foundation for a doctoral scholarship.
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