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Electron-deficient trifluoromethyl-substituted sub-components affect the properties of M4L4 tetrahedral cages

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Struch, N., Topic, F., Rissanen, K., & Lützen, A. (2017). Electron-deficient trifluoromethyl-substituted sub-components affect the properties of M4L4 tetrahedral cages. Dalton Transactions, 46(33), 10809-10813. https://doi.org/10.1039/C7DT02182H
Published in
Dalton Transactions
Authors
Struch, Niklas |
Topic, Filip |
Rissanen, Kari |
Lützen, Arne
Date
2017
Discipline
Orgaaninen kemiaNanoscience CenterOrganic ChemistryNanoscience Center
Copyright
© The Royal Society of Chemistry 2017. This is a final draft version of an article whose final and definitive form has been published by RSC. Published in this repository with the kind permission of the publisher.

 
Two supramolecular tetrahedral cages based on a new electron-deficient trifluoromethyl-substituted pyridylimine ligand are synthesised by sub-component self-assembly. Their structures are characterised by NMR und UV-Vis spectroscopy, high-resolution mass spectrometry and single crystal X-ray diffraction. The iron(II) complex shows host–guest chemistry, complex-to-complex transformations and novel electronic properties.
Publisher
Royal Society of Chemistry
ISSN Search the Publication Forum
1477-9226
Keywords
electron-deficient trifluoromethyl-substituted sub-components
DOI
https://doi.org/10.1039/C7DT02182H
URI

http://urn.fi/URN:NBN:fi:jyu-201708303617

Publication in research information system

https://converis.jyu.fi/converis/portal/detail/Publication/27086079

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  • Matemaattis-luonnontieteellinen tiedekunta [5418]
Related funder(s)
Academy of Finland
Funding program(s)
Research post as Academy Professor, AoF; Research costs of Academy Professor, AoF
Additional information about funding
Financial support from DFG (SFB 813 – Chemistry at Spin Centers) and the Academy of Finland (K. R.: project no's. 263256, 292746 and 265328) is gratefully acknowledged. N. S. thanks Evonik Foundation for a doctoral scholarship.

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