University of Jyväskylä | JYX Digital Repository

  • English  | Give feedback |
    • suomi
    • English
 
  • Login
JavaScript is disabled for your browser. Some features of this site may not work without it.
View Item 
  • JYX
  • Artikkelit
  • Matemaattis-luonnontieteellinen tiedekunta
  • View Item
JYX > Artikkelit > Matemaattis-luonnontieteellinen tiedekunta > View Item

Solid state halogen bonded networks vs. dynamic assemblies in solution: explaining N⋯X interactions of multivalent building blocks

ThumbnailFinal Draft
View/Open
1.2 Mb

Downloads:  
Show download detailsHide download details  
Tero, T.-R., Salorinne, K., Malola, S., Häkkinen, H., & Nissinen, M. (2015). Solid state halogen bonded networks vs. dynamic assemblies in solution: explaining N⋯X interactions of multivalent building blocks. CrystEngComm, 17(43), 8231-8241. https://doi.org/10.1039/C5CE01144B
Published in
CrystEngComm
Authors
Tero, Tiia-Riikka |
Salorinne, Kirsi |
Malola, Sami |
Häkkinen, Hannu |
Nissinen, Maija
Date
2015
Discipline
Fysikaalinen kemiaOrgaaninen kemiaNanoscience CenterPhysical ChemistryOrganic ChemistryNanoscience Center
Copyright
© The Royal Society of Chemistry 2015. This is a final draft version of an article whose final and definitive form has been published by RSC. Published in this repository with the kind permission of the publisher.

 
Tetrapyridine functionalized resorcinarene macrocycles were used as multivalent building blocks for the construction of halogen bonded networks with aryl halide linkers. In the solid state, resorcinarene macrocycles and aryl halide linker molecules assembled into interpenetrated, multidimensional halogen bonded networks with porous structure caused by the 3D block scaffold of the resorcinarenes. 19F NMR spectroscopy proved halogen bond formation also in solution, as either upfield or downfield shifts were observed depending on the bivalent or monovalent halogen bond binding mode. The binding mode in solution was explained by density functional theory computations.
Publisher
Royal Society of Chemistry
ISSN Search the Publication Forum
1466-8033
Keywords
resorcinarene macrocycles aryl halide linkers halogen bonded networks
DOI
https://doi.org/10.1039/C5CE01144B
URI

http://urn.fi/URN:NBN:fi:jyu-201602041451

Publication in research information system

https://converis.jyu.fi/converis/portal/detail/Publication/25290424

Metadata
Show full item record
Collections
  • Matemaattis-luonnontieteellinen tiedekunta [4518]

Related items

Showing items with similar title or keywords.

  • Cation binding resorcinarene bis-crowns: the effect of lower rim alkyl chain length on crystal packing and solid lipid nanoparticles 

    Helttunen, Kaisa; Salorinne, Kirsi; Barboza, Tahnie; Barbosa, Hélène Campos; Suhonen, Aku; Nissinen, Maija (Centre National de la Recherche Scientifique and The Royal Society of Chemistry, 2012)
    A group of seven resorcinarene bis-crown ethers (CNBC5) with two polyether bridges at the upper rim and either propyl, butyl, pentyl, heptyl, nonyl, decyl or undecyl groups at the lower rim were synthesized and their binding ...
  • Halogen bonding and host-guest chemistry between N-alkylammonium resorcinarene halides, diiodoperfluorobutane and neutral guests 

    Pan, Fangfang; Dashti, Mohadeseh; Reynolds, Michael R.; Rissanen, Kari; Trant, John F.; Beyeh, Ngong Kodiah (Beilstein : Institut zur Foerderung der Chemischen Wissenschaften, 2019)
    Single crystal X-ray structures of halogen-bonded assemblies formed between host N-hexylammonium resorcinarene bromide (1) or N-cyclohexylammonium resorcinarene chloride (2), and 1,4-diiodooctafluorobutane and accompanying ...
  • The Effect of Halogen Bonding on the Packing of Bromine Substituted Pyridine and Benzyl Functionalized Resorcinarene Tetrapodands in the Solid State 

    Tero, Tiia-Riikka; Salorinne, Kirsi; Nissinen, Maija (RSC publishing, 2012)
    The synthesis and characterization of new bromine-substituted pyridine and benzyl functionalized tetramethoxy resorcinarene tetrapodands are described and their solid-state structural properties and interactions were studied ...
  • N-Alkyl ammonium resorcinarene salts: multivalent halogen-bonded deep-cavity cavitands 

    Beyeh, Ngong Kodiah; Valkonen, Arto; Bhowmik, Sandip; Pan, Fangfang; Rissanen, Kari (R S C Publications, 2015)
  • Anion-driven encapsulation of cationic guests inside pyridine[4]arene dimers 

    Kiesilä, Anniina; Moilanen, Jani O.; Kruve, Anneli.; Schalley, Christoph A.; Barran, Perdita; Kalenius, Elina (Beilstein Institut zur Foerderung der Chemischen Wissenschaften, 2019)
    Pyridine[4]arenes have previously been considered as anion binding hosts due to the electron-poor nature of the pyridine ring. Herein, we demonstrate the encapsulation of Me4N+ cations inside a dimeric hydrogen-bonded ...
  • Browse materials
  • Browse materials
  • Articles
  • Conferences and seminars
  • Electronic books
  • Historical maps
  • Journals
  • Tunes and musical notes
  • Photographs
  • Presentations and posters
  • Publication series
  • Research reports
  • Research data
  • Study materials
  • Theses

Browse

All of JYXCollection listBy Issue DateAuthorsSubjectsPublished inDepartmentDiscipline

My Account

Login

Statistics

View Usage Statistics
  • How to publish in JYX?
  • Self-archiving
  • Publish Your Thesis Online
  • Publishing Your Dissertation
  • Publication services

Open Science at the JYU
 
Data Protection Description

Accessibility Statement

Unless otherwise specified, publicly available JYX metadata (excluding abstracts) may be freely reused under the CC0 waiver.
Open Science Centre