University of Jyväskylä | JYX Digital Repository

  • English  | Give feedback |
    • suomi
    • English
 
  • Login
JavaScript is disabled for your browser. Some features of this site may not work without it.
View Item 
  • JYX
  • Artikkelit
  • Matemaattis-luonnontieteellinen tiedekunta
  • View Item
JYX > Artikkelit > Matemaattis-luonnontieteellinen tiedekunta > View Item

The Effect of Halogen Bonding on the Packing of Bromine Substituted Pyridine and Benzyl Functionalized Resorcinarene Tetrapodands in the Solid State

ThumbnailFinal Draft
View/Open
1.0 Mb

Downloads:  
Show download detailsHide download details  
Tero, T.-R., Salorinne, K., & Nissinen, M. (2012). The Effect of Halogen Bonding on the Packing of Bromine Substituted Pyridine and Benzyl Functionalized Resorcinarene Tetrapodands in the Solid State. CrystEngComm, 14(21), 7360-7367. https://doi.org/10.1039/C2CE25972A
Published in
CrystEngComm
Authors
Tero, Tiia-Riikka |
Salorinne, Kirsi |
Nissinen, Maija
Date
2012
Discipline
Orgaaninen kemiaNanoscience CenterOrganic ChemistryNanoscience Center
Copyright
© The Royal Society of Chemistry 2012. This is a final draft version of an article whose final and definitive form has been published by RSC. Published in this repository with the kind permission of the publisher.

 
The synthesis and characterization of new bromine-substituted pyridine and benzyl functionalized tetramethoxy resorcinarene tetrapodands are described and their solid-state structural properties and interactions were studied by single crystal X-ray crystallography. Three different crystal structures were obtained for the pyridine derivative and one for the benzyl derivative, which revealed that the interactions of the bromine substituent have an explicit effect on the crystal packing of the resorcinarene molecules. One of the structures obtained had very interesting halogen–halogen interactions with the same geometry as is generally found for compounds used in nonlinear optical studies.
Publisher
RSC publishing
ISSN Search the Publication Forum
1466-8033
Keywords
resorsinareeni supramolekyylikemia halogeenivuorovaikutus resorcinarene halogen interaction supramolekulaarinen kemia

Original source
http://pubs.rsc.org/en/content/articlelanding/2012/ce/c2ce25972a

DOI
https://doi.org/10.1039/C2CE25972A
URI

http://urn.fi/URN:NBN:fi:jyu-201602041440

Publication in research information system

https://converis.jyu.fi/converis/portal/detail/Publication/21648040

Metadata
Show full item record
Collections
  • Matemaattis-luonnontieteellinen tiedekunta [4518]

Related items

Showing items with similar title or keywords.

  • Cation binding resorcinarene bis-crowns: the effect of lower rim alkyl chain length on crystal packing and solid lipid nanoparticles 

    Helttunen, Kaisa; Salorinne, Kirsi; Barboza, Tahnie; Barbosa, Hélène Campos; Suhonen, Aku; Nissinen, Maija (Centre National de la Recherche Scientifique and The Royal Society of Chemistry, 2012)
    A group of seven resorcinarene bis-crown ethers (CNBC5) with two polyether bridges at the upper rim and either propyl, butyl, pentyl, heptyl, nonyl, decyl or undecyl groups at the lower rim were synthesized and their binding ...
  • The Missing Member of the Partially O-Alkylated Resorcinarene Family: Synthesis and Conformation of Methyl Tetramethoxy Resorcinarene 

    Tero, Tiia-Riikka; Suhonen, Aku; Salorinne, Kirsi; Campos-Barbosa, Hélène; Nissinen, Maija (American Chemical Society, 2013)
    An improved Lewis acid catalyzed synthesis method for methyl tetramethoxy resorcinarene is described, which produced the missing lower rim methyl derivative of this partially O-alkylated resorcinarene family. Structural ...
  • A perspective to resorcinarene crowns 

    Tero, Tiia-Riikka; Nissinen, Maija (Elsevier, 2014)
    In this report, we have summarized different synthesis methods of the resorcinarene crowns, discussed their structural and complexation properties together with the possible application aspects.
  • Anion-driven encapsulation of cationic guests inside pyridine[4]arene dimers 

    Kiesilä, Anniina; Moilanen, Jani O.; Kruve, Anneli.; Schalley, Christoph A.; Barran, Perdita; Kalenius, Elina (Beilstein Institut zur Foerderung der Chemischen Wissenschaften, 2019)
    Pyridine[4]arenes have previously been considered as anion binding hosts due to the electron-poor nature of the pyridine ring. Herein, we demonstrate the encapsulation of Me4N+ cations inside a dimeric hydrogen-bonded ...
  • Iodine(i) complexes incorporating sterically bulky 2-substituted pyridines 

    Ward, Jas S.; Gomila, Rosa M.; Frontera, Antonio; Rissanen, Kari (Royal Society of Chemistry (RSC), 2022)
    The silver(I) and iodine(I) complexes of the 2-substituted pyridines 2-(diphenylmethyl)pyridine (1) and 2-(1,1-diphenylethyl)pyridine (2), along with their potential protonated side products, were synthesised to investigate ...
  • Browse materials
  • Browse materials
  • Articles
  • Conferences and seminars
  • Electronic books
  • Historical maps
  • Journals
  • Tunes and musical notes
  • Photographs
  • Presentations and posters
  • Publication series
  • Research reports
  • Research data
  • Study materials
  • Theses

Browse

All of JYXCollection listBy Issue DateAuthorsSubjectsPublished inDepartmentDiscipline

My Account

Login

Statistics

View Usage Statistics
  • How to publish in JYX?
  • Self-archiving
  • Publish Your Thesis Online
  • Publishing Your Dissertation
  • Publication services

Open Science at the JYU
 
Data Protection Description

Accessibility Statement

Unless otherwise specified, publicly available JYX metadata (excluding abstracts) may be freely reused under the CC0 waiver.
Open Science Centre