The Missing Member of the Partially O-Alkylated Resorcinarene Family: Synthesis and Conformation of Methyl Tetramethoxy Resorcinarene

Tero, Tiia-Riikka; Suhonen, Aku; Salorinne, Kirsi; Campos-Barbosa, Hélène; Nissinen, Maija

doi:10.1021/ol400118t

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Tero, T.-R., Suhonen, A., Salorinne, K., Campos-Barbosa, H., & Nissinen, M. (2013). The Missing Member of the Partially O-Alkylated Resorcinarene Family: Synthesis and Conformation of Methyl Tetramethoxy Resorcinarene. Organic Letters, 15(5), 1096-1099. https://doi.org/10.1021/ol400118t

Julkaistu sarjassa

Organic Letters

Tekijät

Tero, Tiia-Riikka |

Suhonen, Aku |

Salorinne, Kirsi |

Campos-Barbosa, Hélène |

Nissinen, Maija

Päivämäärä

2013

Oppiaine

Orgaaninen kemia Nanoscience Center Organic Chemistry Nanoscience Center

Tekijänoikeudet

© 2013 American Chemical Society. This is a final draft version of an article whose final and definitive form has been published by ACS. Published in this repository with the kind permission of the publisher.

An improved Lewis acid catalyzed synthesis method for methyl tetramethoxy resorcinarene is described, which produced the missing lower rim methyl derivative of this partially O-alkylated resorcinarene family. Structural characterization by means of variable temperature NMR experiments and single crystal X-ray diffraction studies furthermore revealed that the resorcinarene core adopts different conformations in the solid state and in solution.

Julkaisija

American Chemical Society

ISSN Hae Julkaisufoorumista

1523-7060

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