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The Missing Member of the Partially O-Alkylated Resorcinarene Family: Synthesis and Conformation of Methyl Tetramethoxy Resorcinarene

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Tero, T.-R., Suhonen, A., Salorinne, K., Campos-Barbosa, H., & Nissinen, M. (2013). The Missing Member of the Partially O-Alkylated Resorcinarene Family: Synthesis and Conformation of Methyl Tetramethoxy Resorcinarene. Organic Letters, 15(5), 1096-1099. https://doi.org/10.1021/ol400118t
Published in
Organic Letters
Authors
Tero, Tiia-Riikka |
Suhonen, Aku |
Salorinne, Kirsi |
Campos-Barbosa, Hélène |
Nissinen, Maija
Date
2013
Discipline
Orgaaninen kemiaNanoscience CenterOrganic ChemistryNanoscience Center
Copyright
© 2013 American Chemical Society. This is a final draft version of an article whose final and definitive form has been published by ACS. Published in this repository with the kind permission of the publisher.

 
An improved Lewis acid catalyzed synthesis method for methyl tetramethoxy resorcinarene is described, which produced the missing lower rim methyl derivative of this partially O-alkylated resorcinarene family. Structural characterization by means of variable temperature NMR experiments and single crystal X-ray diffraction studies furthermore revealed that the resorcinarene core adopts different conformations in the solid state and in solution.
Publisher
American Chemical Society
ISSN Search the Publication Forum
1523-7060
Keywords
resorsinareeni tetrametoksiresorsinareeni supramolekyylikemia resorcinarene tetramethoxy resorcinarene supramolekulaarinen kemia

Original source
http://dx.doi.org/10.1021/ol400118t

DOI
https://doi.org/10.1021/ol400118t
URI

http://urn.fi/URN:NBN:fi:jyu-201602041453

Publication in research information system

https://converis.jyu.fi/converis/portal/detail/Publication/22375514

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  • Matemaattis-luonnontieteellinen tiedekunta [4518]

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