| dc.contributor.author | Hänninen, Mikko M. | |
| dc.contributor.author | Paturi, Petriina | |
| dc.contributor.author | Tuononen, Heikki | |
| dc.contributor.author | Sillanpää, Reijo | |
| dc.contributor.author | Lehtonen, Ari | |
| dc.date.accessioned | 2015-11-30T07:38:50Z | |
| dc.date.available | 2015-11-30T07:38:50Z | |
| dc.date.issued | 2013 | |
| dc.identifier.citation | Hänninen, M. M., Paturi, P., Tuononen, H., Sillanpää, R., & Lehtonen, A. (2013). Heptacoordinated Molybdenum(VI) Complexes of Phenylenediamine Bis(phenolate): A Stable Molybdenum Amidophenoxide Radical. <i>Inorganic Chemistry</i>, <i>52</i>(10), 5714-5721. <a href="https://doi.org/10.1021/ic302355b" target="_blank">https://doi.org/10.1021/ic302355b</a> | |
| dc.identifier.other | CONVID_22809710 | |
| dc.identifier.other | TUTKAID_57736 | |
| dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/47853 | |
| dc.description.abstract | The syntheses, crystallographic structures, magnetic properties, and theoretical studies of two heptacoordinated molybdenum complexes with N,N′-bis(3,5-di-tert-butyl-2-hydroxyphenyl)-1,2-phenylenediamine (H4N2O2) are reported. A formally molybdenum(VI) complex [Mo(N2O2)Cl2(dmf)] (1) was synthesized by the reaction between [MoO2Cl2(dmf)2] and H4N2O2, whereas the other molybdenum(VI) complex [Mo(N2O2)(HN2O2)] (2) was formed when [MoO2(acac)2] was used as a molybdenum source. Both complexes represent a rare case of the MoVI ion without any multiply bonded terminal ligands. In addition, molecular structures, magnetic measurements, ESR spectroscopy, and density functional theory calculations indicate that complex 2 is the first stable molybdenum(VI) amidophenoxide radical. | |
| dc.language.iso | eng | |
| dc.publisher | American Chemical Society | |
| dc.relation.ispartofseries | Inorganic Chemistry | |
| dc.subject.other | radikaalit | |
| dc.subject.other | amidofenoksidi | |
| dc.subject.other | syylliset ligandit | |
| dc.subject.other | radical | |
| dc.subject.other | amidophenoxide | |
| dc.subject.other | non-innocent ligands | |
| dc.title | Heptacoordinated Molybdenum(VI) Complexes of Phenylenediamine Bis(phenolate): A Stable Molybdenum Amidophenoxide Radical | |
| dc.type | article | |
| dc.identifier.urn | URN:NBN:fi:jyu-201511243797 | |
| dc.contributor.laitos | Kemian laitos | fi |
| dc.contributor.laitos | Department of Chemistry | en |
| dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
| dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
| dc.date.updated | 2015-11-24T13:15:26Z | |
| dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
| dc.description.reviewstatus | peerReviewed | |
| dc.format.pagerange | 5714-5721 | |
| dc.relation.issn | 0020-1669 | |
| dc.relation.numberinseries | 10 | |
| dc.relation.volume | 52 | |
| dc.type.version | acceptedVersion | |
| dc.rights.copyright | © 2013 American Chemical Society. This is a final draft version of an article whose final and definitive form has been published by ACS. Published in this repository with the kind permission of the publisher. | |
| dc.rights.accesslevel | openAccess | fi |
| dc.subject.yso | molybdeeni | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p11107 | |
| dc.relation.doi | 10.1021/ic302355b | |
| dc.type.okm | A1 | |
