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dc.contributor.authorHänninen, Mikko M.
dc.contributor.authorPaturi, Petriina
dc.contributor.authorTuononen, Heikki
dc.contributor.authorSillanpää, Reijo
dc.contributor.authorLehtonen, Ari
dc.date.accessioned2015-11-30T07:38:50Z
dc.date.available2015-11-30T07:38:50Z
dc.date.issued2013
dc.identifier.citationHänninen, M. M., Paturi, P., Tuononen, H., Sillanpää, R., & Lehtonen, A. (2013). Heptacoordinated Molybdenum(VI) Complexes of Phenylenediamine Bis(phenolate): A Stable Molybdenum Amidophenoxide Radical. <i>Inorganic Chemistry</i>, <i>52</i>(10), 5714-5721. <a href="https://doi.org/10.1021/ic302355b" target="_blank">https://doi.org/10.1021/ic302355b</a>
dc.identifier.otherCONVID_22809710
dc.identifier.otherTUTKAID_57736
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/47853
dc.description.abstractThe syntheses, crystallographic structures, magnetic properties, and theoretical studies of two heptacoordinated molybdenum complexes with N,N′-bis(3,5-di-tert-butyl-2-hydroxyphenyl)-1,2-phenylenediamine (H4N2O2) are reported. A formally molybdenum(VI) complex [Mo(N2O2)Cl2(dmf)] (1) was synthesized by the reaction between [MoO2Cl2(dmf)2] and H4N2O2, whereas the other molybdenum(VI) complex [Mo(N2O2)(HN2O2)] (2) was formed when [MoO2(acac)2] was used as a molybdenum source. Both complexes represent a rare case of the MoVI ion without any multiply bonded terminal ligands. In addition, molecular structures, magnetic measurements, ESR spectroscopy, and density functional theory calculations indicate that complex 2 is the first stable molybdenum(VI) amidophenoxide radical.
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.relation.ispartofseriesInorganic Chemistry
dc.subject.otherradikaalit
dc.subject.otheramidofenoksidi
dc.subject.othersyylliset ligandit
dc.subject.otherradical
dc.subject.otheramidophenoxide
dc.subject.othernon-innocent ligands
dc.titleHeptacoordinated Molybdenum(VI) Complexes of Phenylenediamine Bis(phenolate): A Stable Molybdenum Amidophenoxide Radical
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201511243797
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2015-11-24T13:15:26Z
dc.type.coarjournal article
dc.description.reviewstatuspeerReviewed
dc.format.pagerange5714-5721
dc.relation.issn0020-1669
dc.relation.numberinseries10
dc.relation.volume52
dc.type.versionacceptedVersion
dc.rights.copyright© 2013 American Chemical Society. This is a final draft version of an article whose final and definitive form has been published by ACS. Published in this repository with the kind permission of the publisher.
dc.rights.accesslevelopenAccessfi
dc.subject.ysomolybdeeni
jyx.subject.urihttp://www.yso.fi/onto/yso/p11107
dc.relation.doi10.1021/ic302355b


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