dc.contributor.author | Valkonen, Arto | |
dc.contributor.author | Chukhlieb, Maryna | |
dc.contributor.author | Moilanen, Jani | |
dc.contributor.author | Tuononen, Heikki | |
dc.contributor.author | Rissanen, Kari | |
dc.date.accessioned | 2015-11-25T12:05:50Z | |
dc.date.available | 2015-11-25T12:05:50Z | |
dc.date.issued | 2013 | |
dc.identifier.citation | Valkonen, A., Chukhlieb, M., Moilanen, J., Tuononen, H., & Rissanen, K. (2013). Halogen and Hydrogen Bonded Complexes of 5-Iodouracil. <i>Crystal Growth and Design</i>, <i>13</i>(11), 4769-4775. <a href="https://doi.org/10.1021/cg400924n" target="_blank">https://doi.org/10.1021/cg400924n</a> | |
dc.identifier.other | CONVID_22955229 | |
dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/47829 | |
dc.description.abstract | Three derivatives of 5-iodouracil were prepared, and their complexation properties, supplemented by 5-iodouracil under the same conditions, were studied with and without halogen bond acceptors in N,N-dimethylformamide, N,N-diethylformamide, N-methylformamide, formamide, dimethylsulfoxide, and water. The intermolecular halogen and hydrogen bonding interactions observed in the solid state were investigated using single crystal X-ray diffraction and quantum chemical calculations, and the acquired data were contrasted with bonding interactions previously reported for 5-iodouracil in the Cambridge Structural Database. It was found that the polarized iodine atom and the amidic NH functionality act simultaneously in 5-iodouracil and its derivatives, for which reason the halogen and hydrogen bonds play an equally important role in controlling the resulting crystal structures. | |
dc.language.iso | eng | |
dc.publisher | American Chemical Society | |
dc.relation.ispartofseries | Crystal Growth and Design | |
dc.subject.other | halogeenisidokset | |
dc.subject.other | 5-jodourasiili | |
dc.subject.other | hydrogen bonding | |
dc.subject.other | halogen bonding | |
dc.subject.other | 5-iodouracil | |
dc.title | Halogen and Hydrogen Bonded Complexes of 5-Iodouracil | |
dc.type | research article | |
dc.identifier.urn | URN:NBN:fi:jyu-201511243793 | |
dc.contributor.laitos | Kemian laitos | fi |
dc.contributor.laitos | Department of Chemistry | en |
dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
dc.contributor.oppiaine | Orgaaninen kemia | fi |
dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
dc.contributor.oppiaine | Organic Chemistry | en |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
dc.date.updated | 2015-11-24T13:15:14Z | |
dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
dc.description.reviewstatus | peerReviewed | |
dc.format.pagerange | 4769-4775 | |
dc.relation.issn | 1528-7483 | |
dc.relation.numberinseries | 11 | |
dc.relation.volume | 13 | |
dc.type.version | acceptedVersion | |
dc.rights.copyright | © 2013 American Chemical Society. This is a final draft version of an article whose final and definitive form has been published by ACS. Published in this repository with the kind permission of the publisher. | |
dc.rights.accesslevel | openAccess | fi |
dc.type.publication | article | |
dc.subject.yso | vetysidokset | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p38131 | |
dc.relation.doi | 10.1021/cg400924n | |
dc.type.okm | A1 | |