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dc.contributor.authorDube, Jonathan
dc.contributor.authorHänninen, Mikko M.
dc.contributor.authorDutton, Jason
dc.contributor.authorTuononen, Heikki
dc.contributor.authorRagogna, Paul
dc.date.accessioned2015-11-25T08:02:31Z
dc.date.available2015-11-25T08:02:31Z
dc.date.issued2012
dc.identifier.citationDube, J., Hänninen, M. M., Dutton, J., Tuononen, H., & Ragogna, P. (2012). Homoleptic Pnictogen-Chalcogen Coordination Complexes. <i>Inorganic Chemistry</i>, <i>51</i>(16), 8897-8903. <a href="https://doi.org/10.1021/ic300892p" target="_blank">https://doi.org/10.1021/ic300892p</a>
dc.identifier.otherCONVID_21746937
dc.identifier.otherTUTKAID_53107
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/47815
dc.description.abstractThe synthesis and structural characterization of dicationic selenium and tellurium analogues of the carbodiphosphorane and triphosphenium families of compounds are reported. These complexes, [Ch(dppe)][OTf]2 [Ch = Se, Te; dppe = 1,2-bis(diphenylphosphino)ethane; OTf = trifluoromethanesulfonate], are formed using [Ch]2+ reagents via a ligand-exchange protocol and represent extremely rare examples of homoleptic pnictogen → chalcogen coordination complexes. The corresponding arsenic compounds were also prepared, [Ch(dpAse)][OTf]2 [Ch = Se, Te; dpAse = 1,2-bis(diphenylarsino)ethane], exhibiting the first instance of an arsenic → chalcogen dative bond. The electronic structures of these unique compounds were determined and compared to previously reported chalcogen dications.
dc.language.isoeng
dc.publisherACS
dc.relation.ispartofseriesInorganic Chemistry
dc.subject.otherpniktogeeni-kalkogeeni -kompleksit
dc.subject.otherpnictogen-chalcogen complexes
dc.titleHomoleptic Pnictogen-Chalcogen Coordination Complexes
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201511243788
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemiafi
dc.contributor.oppiaineInorganic and Analytical Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2015-11-24T10:15:26Z
dc.type.coarhttp://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatuspeerReviewed
dc.format.pagerange8897-8903
dc.relation.issn0020-1669
dc.relation.numberinseries16
dc.relation.volume51
dc.type.versionacceptedVersion
dc.rights.copyright© 2012 American Chemical Society. This is a final draft version of an article whose final and definitive form has been published by ACS. Published in this repository with the kind permission of the publisher.
dc.rights.accesslevelopenAccessfi
dc.relation.doi10.1021/ic300892p
dc.type.okmA1


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