| dc.contributor.author | Dube, Jonathan | |
| dc.contributor.author | Hänninen, Mikko M. | |
| dc.contributor.author | Dutton, Jason | |
| dc.contributor.author | Tuononen, Heikki | |
| dc.contributor.author | Ragogna, Paul | |
| dc.date.accessioned | 2015-11-25T08:02:31Z | |
| dc.date.available | 2015-11-25T08:02:31Z | |
| dc.date.issued | 2012 | |
| dc.identifier.citation | Dube, J., Hänninen, M. M., Dutton, J., Tuononen, H., & Ragogna, P. (2012). Homoleptic Pnictogen-Chalcogen Coordination Complexes. <i>Inorganic Chemistry</i>, <i>51</i>(16), 8897-8903. <a href="https://doi.org/10.1021/ic300892p" target="_blank">https://doi.org/10.1021/ic300892p</a> | |
| dc.identifier.other | CONVID_21746937 | |
| dc.identifier.other | TUTKAID_53107 | |
| dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/47815 | |
| dc.description.abstract | The synthesis and structural characterization of dicationic selenium and tellurium analogues of the carbodiphosphorane and triphosphenium families of compounds are reported. These complexes, [Ch(dppe)][OTf]2 [Ch = Se, Te; dppe = 1,2-bis(diphenylphosphino)ethane; OTf = trifluoromethanesulfonate], are formed using [Ch]2+ reagents via a ligand-exchange protocol and represent extremely rare examples of homoleptic pnictogen → chalcogen coordination complexes. The corresponding arsenic compounds were also prepared, [Ch(dpAse)][OTf]2 [Ch = Se, Te; dpAse = 1,2-bis(diphenylarsino)ethane], exhibiting the first instance of an arsenic → chalcogen dative bond. The electronic structures of these unique compounds were determined and compared to previously reported chalcogen dications. | |
| dc.language.iso | eng | |
| dc.publisher | ACS | |
| dc.relation.ispartofseries | Inorganic Chemistry | |
| dc.subject.other | pniktogeeni-kalkogeeni -kompleksit | |
| dc.subject.other | pnictogen-chalcogen complexes | |
| dc.title | Homoleptic Pnictogen-Chalcogen Coordination Complexes | |
| dc.type | article | |
| dc.identifier.urn | URN:NBN:fi:jyu-201511243788 | |
| dc.contributor.laitos | Kemian laitos | fi |
| dc.contributor.laitos | Department of Chemistry | en |
| dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
| dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
| dc.date.updated | 2015-11-24T10:15:26Z | |
| dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
| dc.description.reviewstatus | peerReviewed | |
| dc.format.pagerange | 8897-8903 | |
| dc.relation.issn | 0020-1669 | |
| dc.relation.numberinseries | 16 | |
| dc.relation.volume | 51 | |
| dc.type.version | acceptedVersion | |
| dc.rights.copyright | © 2012 American Chemical Society. This is a final draft version of an article whose final and definitive form has been published by ACS. Published in this repository with the kind permission of the publisher. | |
| dc.rights.accesslevel | openAccess | fi |
| dc.relation.doi | 10.1021/ic300892p | |
| dc.type.okm | A1 | |
