dc.contributor.author | Fan, Cheng | |
dc.contributor.author | Mercier, Lauren | |
dc.contributor.author | Piers, Warren | |
dc.contributor.author | Tuononen, Heikki | |
dc.contributor.author | Parvez, Masood | |
dc.date.accessioned | 2015-11-24T12:06:58Z | |
dc.date.available | 2015-11-24T12:06:58Z | |
dc.date.issued | 2010 | |
dc.identifier.citation | Fan, C., Mercier, L., Piers, W., Tuononen, H., & Parvez, M. (2010). Dihydrogen Activation by Antiaromatic Pentaarylboroles. <i>Journal of the American Chemical Society</i>, <i>132</i>(28), 9604-9606. <a href="https://doi.org/10.1021/ja105075h" target="_blank">https://doi.org/10.1021/ja105075h</a> | |
dc.identifier.other | CONVID_20144836 | |
dc.identifier.other | TUTKAID_43886 | |
dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/47801 | |
dc.description.abstract | Facile metal-free splitting of molecular hydrogen (H2) is crucial for the utilization of H2 without the need for toxic transition-metal-based catalysts. Frustrated Lewis pairs (FLPs) are a new class of hydrogen activators wherein interactions with both a Lewis acid and a Lewis base heterolytically disrupt the hydrogen−hydrogen bond. Here we describe the activation of hydrogen exclusively by a boron-based Lewis acid, perfluoropentaphenylborole. This antiaromatic compound reacts extremely rapidly with H2 in both solution and the solid state to yield boracyclopent-3-ene products resulting from addition of hydrogen atoms to the carbons α to boron in the starting borole. The disruption of antiaromaticity upon reaction of the borole with H2 provides a significant thermodynamic driving force for this new metal-free hydrogen-splitting reaction. | |
dc.language.iso | eng | |
dc.publisher | ACS | |
dc.relation.ispartofseries | Journal of the American Chemical Society | |
dc.subject.other | vedyn aktivointi | |
dc.subject.other | penta-aryyliborrolit | |
dc.subject.other | hydrogen activation | |
dc.subject.other | pentaarylboroles | |
dc.title | Dihydrogen Activation by Antiaromatic Pentaarylboroles | |
dc.type | article | |
dc.identifier.urn | URN:NBN:fi:jyu-201511243773 | |
dc.contributor.laitos | Kemian laitos | fi |
dc.contributor.laitos | Department of Chemistry | en |
dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
dc.date.updated | 2015-11-24T07:15:08Z | |
dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
dc.description.reviewstatus | peerReviewed | |
dc.format.pagerange | 9604-9606 | |
dc.relation.issn | 0002-7863 | |
dc.relation.numberinseries | 28 | |
dc.relation.volume | 132 | |
dc.type.version | acceptedVersion | |
dc.rights.copyright | © 2010 American Chemical Society. This is a final draft version of an article whose final and definitive form has been published by ACS. Published in this repository with the kind permission of the publisher. | |
dc.rights.accesslevel | openAccess | fi |
dc.relation.doi | 10.1021/ja105075h | |
dc.type.okm | A1 | |