Do Extremely Bent Allenes Exist?
Hänninen, M. M., Peuronen, A., & Tuononen, H. (2009). Do Extremely Bent Allenes Exist?. Chemistry - A European Journal, 15(30), 7287-7291. https://doi.org/10.1002/chem.200900928
Published inChemistry - A European Journal
© 2009 Wiley-VCH Verlag GmbH & Co. This is a final draft version of an article whose final and definitive form has been published by Wiley. Published in this repository with the kind permission of the publisher.
Bent allenes: Theoretical calculations show that extremely bent allenes, cyclic or acyclic, adopt a ground state that only bears a formal relationship to classical allenes. Consequently, five-membered ring allenes favor a carbene-like electronic structure and formally contain a trivalent carbon(II) center.
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