Do Extremely Bent Allenes Exist?
Abstract
Bent allenes: Theoretical calculations show that extremely bent allenes, cyclic or acyclic, adopt a ground state that only bears a formal relationship to classical allenes. Consequently, five-membered ring allenes favor a carbene-like electronic structure and formally contain a trivalent carbon(II) center.
Main Authors
Format
Articles
Research article
Published
2009
Series
Subjects
Publication in research information system
Publisher
Wiley
The permanent address of the publication
https://urn.fi/URN:NBN:fi:jyu-201511203752Käytä tätä linkitykseen.
Review status
Peer reviewed
ISSN
0947-6539
DOI
https://doi.org/10.1002/chem.200900928
Language
English
Published in
Chemistry - A European Journal
Citation
- Hänninen, M. M., Peuronen, A., & Tuononen, H. (2009). Do Extremely Bent Allenes Exist?. Chemistry - A European Journal, 15(30), 7287-7291. https://doi.org/10.1002/chem.200900928
License
Copyright© 2009 Wiley-VCH Verlag GmbH & Co. This is a final draft version of an article whose final and definitive form has been published by Wiley. Published in this repository with the kind permission of the publisher.