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dc.contributor.authorLy, Hanh
dc.contributor.authorTuononen, Heikki
dc.contributor.authorParvez, Masood
dc.contributor.authorRoesler, Roland
dc.date.accessioned2015-11-20T09:48:48Z
dc.date.available2015-11-20T09:48:48Z
dc.date.issued2008
dc.identifier.citationLy, H., Tuononen, H., Parvez, M., & Roesler, R. (2008). Unusual B4N2C2 Ligand in a Ruthenium Pseudo-Triple-Decker Sandwich Complex Displaying Three Reversible Electron-Transfer Steps. <em>Angewandte Chemie, International Edition</em>, 47 (2), 361-364. <a href="http://dx.doi.org/10.1002/anie.200703556">doi:10.1002/anie.200703556</a>
dc.identifier.otherTUTKAID_28499
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/47770
dc.description.abstractOpen, sesame: The reaction of a heterobicyclic pentalenediyl-like Me2Ph4B4N2C2 dianion with [{(C5Me5)RuCl}4] cleaves the N[BOND]N bond of the ligand and affords a pseudo-triple-decker sandwich complex containing a B4N2C2 middle deck (see picture). This eight-membered ring features nearly linear B-N-B moieties and brings the ruthenium centers unusually close. Cyclic voltammetry indicates efficient electron delocalization over the framework.
dc.language.isoeng
dc.publisherWiley
dc.relation.ispartofseriesAngewandte Chemie, International Edition
dc.subject.otherruteenikompleksi
dc.subject.otherboori-typpi yhdisteet
dc.subject.otherruthenium complex
dc.subject.otherboron-nitrogen compounds
dc.titleUnusual B4N2C2 Ligand in a Ruthenium Pseudo-Triple-Decker Sandwich Complex Displaying Three Reversible Electron-Transfer Steps
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-201511193721
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.contributor.oppiaineEpäorgaaninen ja analyyttinen kemia
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.date.updated2015-11-19T10:15:10Z
dc.type.coarjournal article
dc.description.reviewstatuspeerReviewed
dc.format.pagerange361-364
dc.relation.issn1433-7851
dc.relation.volume47
dc.type.versionacceptedVersion
dc.rights.copyright© 2008 Wiley-VCH Verlag GmbH & Co. This is a final draft version of an article whose final and definitive form has been published by Wiley. Published in this repository with the kind permission of the publisher.
dc.rights.accesslevelopenAccessfi
dc.relation.doi10.1002/anie.200703556


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