Mixed valence mono- and hetero-metallic grid catenanes
Giri, C., Topic, F., Cametti, M., & Rissanen, K. (2015). Mixed valence mono- and hetero-metallic grid catenanes. Chemical Science, 6(10), 5712-5718. https://doi.org/10.1039/C5SC01851J
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© 2015 The Authors. Published by The Royal Society of Chemistry. This is an open access article distributed under the Creative Commons Attribution 3.0. License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work in properly cited. The Creative Commons Public Domain Dedication waiver applies to the data made available in this article, unless otherwise stated.
Here, we report on the multicomponent self-assembly and single crystal X-ray diffraction study of
a series of three interlocked mixed valence mono- and hetero-metallic [2]-catenanes made of
[2 2] metallo-grids. They show unique structural features and highlight the essential roles of
both the Cu(II)/Cu(I) pair and of the conformationally adaptable organic ligands for achieving
catenation of grids.
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Except where otherwise noted, this item's license is described as © 2015 The Authors. Published by The Royal Society of Chemistry. This is an open access article distributed under the Creative Commons Attribution 3.0. License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work in properly cited. The Creative Commons Public Domain Dedication waiver applies to the data made available in this article, unless otherwise stated.