Mixed valence mono- and hetero-metallic grid catenanes

Giri, Chandan; Topic, Filip; Cametti, Massimo; Rissanen, Kari

doi:10.1039/C5SC01851J

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Giri, C., Topic, F., Cametti, M., & Rissanen, K. (2015). Mixed valence mono- and hetero-metallic grid catenanes. Chemical Science, 6(10), 5712-5718. https://doi.org/10.1039/C5SC01851J

Julkaistu sarjassa

Chemical Science

Tekijät

Giri, Chandan |

Topic, Filip |

Cametti, Massimo |

Rissanen, Kari

Päivämäärä

2015

Oppiaine

Orgaaninen kemia Nanoscience Center Organic Chemistry Nanoscience Center

Tekijänoikeudet

© 2015 The Authors. Published by The Royal Society of Chemistry. This is an open access article distributed under the Creative Commons Attribution 3.0. License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work in properly cited. The Creative Commons Public Domain Dedication waiver applies to the data made available in this article, unless otherwise stated.

Here, we report on the multicomponent self-assembly and single crystal X-ray diffraction study of a series of three interlocked mixed valence mono- and hetero-metallic [2]-catenanes made of [2 2] metallo-grids. They show unique structural features and highlight the essential roles of both the Cu(II)/Cu(I) pair and of the conformationally adaptable organic ligands for achieving catenation of grids.

Julkaisija

RSC Publications

ISSN Hae Julkaisufoorumista

2041-6520

Lisenssi

© 2015 The Authors. Published by The Royal Society of Chemistry. This is an open access article distributed under the Creative Commons Attribution 3.0. License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work in properly cited. The Creative Commons Public Domain Dedication waiver applies to the data made available in this article, unless otherwise stated.

Ellei muuten mainita, aineiston lisenssi on © 2015 The Authors. Published by The Royal Society of Chemistry. This is an open access article distributed under the Creative Commons Attribution 3.0. License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work in properly cited. The Creative Commons Public Domain Dedication waiver applies to the data made available in this article, unless otherwise stated.