Packing incentives and a reliable N–H...N–pyridine synthon in co-crystallization of bipyridines with two agrochemical actives
Nauha, E., Kolehmainen, E., & Nissinen, M. (2011). Packing incentives and a reliable N–H...N–pyridine synthon in co-crystallization of bipyridines with two agrochemical actives. CrystEngComm, 13(21), 6531-6537. https://doi.org/10.1039/C1CE05730H
Julkaistu sarjassa
CrystEngCommPäivämäärä
2011Tekijänoikeudet
© The Royal Society of Chemistry 2011. This is an electronic final draft version of an article whose final and definitive form has been published in CrystEngComm by RSC.
The co-crystallization of agrochemical actives thiophanate-methyl and thiophanate-ethyl with 2,2′-bipyridine, 4,4′-bipyridine and 1,2-bis(4-pyridyl)ethane was investigated with conventional crystallization, the slurry method and liquid-assisted grinding. Co-crystals of both thiophanates with all bipyridines were found and the structures solved with single crystal X-ray diffraction. Whereas the 2,2′-bipyridine co-crystals seem to form because of a combination of weak interactions, and in the case of the thiophanate-methyl, partly because of close packing incentives, the 4,4′-bipyridine and 1,2-bis(4-pyridyl)ethane co-crystals form mainly because of a favourable N–H···N–pyridine hydrogen bonding synthon.
Julkaisija
RSCISSN Hae Julkaisufoorumista
1466-8033Asiasanat
Julkaisu tutkimustietojärjestelmässä
https://converis.jyu.fi/converis/portal/detail/Publication/20800636
Metadata
Näytä kaikki kuvailutiedotKokoelmat
Samankaltainen aineisto
Näytetään aineistoja, joilla on samankaltainen nimeke tai asiasanat.
-
Co-crystals of an agrochemical active – A pyridine-amine synthon for a thioamide group
Nauha, Elisa; Nissinen, Maija (Elsevier, 2011)Five novel co-crystals of thiophanate-ethyl (TE), an agrochemical active, with di(2-pyridyl)ketone (1), 2-benzoylpyridine (2), 3-benzoylpyridine (3), 4-phenylpyridine (4) and biphenyl (5) were found and crystal structures ... -
Crystalline forms of selected agrochemical actives : design and synthesis of cocrystals
Nauha, Elisa (University of Jyväskylä, 2012)The research described in this disseration covers the crystal form screening of two analogous agrochemical actives, thiophanate-methyl and thiophanate-ethyl, as well as the discovery of seven 4-hydroxybenzoic acid ... -
Preparation of potentially porous, chiral organometallic materials through spontaneous resolution of pincer palladium conformers
Johnson, Magnus T.; Dzolic, Zoran; Cetina, Mario; Lahtinen, Manu; Ahlquist, Mårten S. G.; Rissanen, Kari; Öhrström, Lars; Wendt, Ola F. (Royal Society of Chemistry, 2013)Understanding the mechanism by which advanced materials assemble is essential for the design of new materials with desired properties. Here, we report a method to form chiral, potentially porous materials through spontaneous ... -
Development of ultrasound-assisted digestion methods for the determination of toxic element concentrations in ash samples by ICP-OES
Ilander, Aki (University of Jyväskylä, 2011)The present thesis introduces several ultrasound-assisted digestion methods developed for the determination of toxic element concentrations in ash samples by inductively coupled plasma optical emission spectrometry (ICP-OES). ... -
Crystal structures of 2,2'-bipyridin-1-ium 1,1,3,3-tetracyano-2-ethoxyprop-2-en-1-ide and bis(2,2'-bipyridin-1-ium) 1,1,3,3-tetracyano-2-(dicyanomethylene)propane-1,3-diide
Setifi, Zouaoui; Valkonen, Arto; Fernandes, Manuel A.; Nummelin, Sami; Boughzala, Habib; Setifi, Fatima; Glidewell, Christopher (International Union of Crystallography, 2015)In 2,20 -bipyridin-1-ium 1,1,3,3-tetracyano-2-ethoxyprop-2-en-1-ide, C10H9N2 + - C9H5N4O, (I), the ethyl group in the anion is disordered over two sets of atomic sites with occupancies 0.634 (9) and 0.366 (9), and the ...
Ellei toisin mainittu, julkisesti saatavilla olevia JYX-metatietoja (poislukien tiivistelmät) saa vapaasti uudelleenkäyttää CC0-lisenssillä.