Matemaattis-luonnontieteellinen tiedekunta: Recent submissions
Now showing items 136-140 of 6106
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Structural Isomerism in Bimetallic Ag20Cu12 Nanoclusters
(American Chemical Society (ACS), 2024)Structural isomers of atomically precise metal nanoclusters are highly sought after for investigating structure–property relationships in nanostructured materials. However, they are extremely rare, particularly those of ... -
Synthesis and crystallization of a carboxylate functionalized N-heterocyclic carbene-based Au13 cluster with strong photo-luminescence
(Royal Society of Chemistry (RSC), 2024)Here we report the synthesis and crystallization of a –COOH-capped N-heterocyclic carbene (NHC)-protected Au13 cluster. The single-crystal structure of the –COOH-capped NHC-Au13 cluster reveals a classic icosahedral core ... -
A refactored biosynthetic pathway for the production of glycosylated microbial sunscreens
(Royal Society of Chemistry (RSC), 2024)Mycosporine-like amino acids (MAAs) are a family of water-soluble and colorless secondary metabolites, with high extinction coefficients, that function as microbial sunscreens. MAAs share a cyclohexinimine chromophore that ... -
The impact of preoperative treatments on the immune environment of rectal cancer
(Wiley-Blackwell, 2024)To improve local disease control, the use of preoperative radiotherapy either alone or combined with chemotherapy has become standard practice in rectal cancer, but it is unclear how these treatments modify the antitumoral ... -
Winter is not coming : evaluating impacts of changing winter conditions on coregonine reproductive phenology
(EDP Sciences, 2024)Fishes in northern latitude lakes are at risk from climate-induced warming because the seasonality in water temperature is degrading, which can change ecosystem properties and the phenology of life-history events. ...