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dc.contributor.authorMarttinen, Antti
dc.contributor.authorLahtinen, Manu
dc.date.accessioned2024-06-19T09:15:27Z
dc.date.available2024-06-19T09:15:27Z
dc.date.issued2024
dc.identifier.citationMarttinen, A., & Lahtinen, M. (2024). Aqueous syntheses of anthracene-based mixed-ligand coordination polymers and their structural and optical properties. <i>CrystEngComm</i>, <i>Early online</i>. <a href="https://doi.org/10.1039/d4ce00399c" target="_blank">https://doi.org/10.1039/d4ce00399c</a>
dc.identifier.otherCONVID_220758471
dc.identifier.urihttps://jyx.jyu.fi/handle/123456789/96020
dc.description.abstractSeries of mixed-ligand coordination polymers (CP) and metal–organic frameworks (MOFs) based on bulky 9,10-di(1H-imidazol-1-yl)anthracene (dia) were synthesized from aqueous solutions even with very short (<10 min) reaction times. Two different metals (M = Cu, Ni) and three different secondary ligands were used to generate six new structures: [Cu2(dia)2(5-aip)2]·6H2O (1), [Ni2(dia)2(5-aip)2]·5H2O (2), [Cu2(dia)2(2-ata)2]·4H2O (3), [Ni(dia)(2-ata)·Ni(dia)2(2-ata)]·2.5H2O (4), [Cu8(dia)2(5-sip)4(OH)4] (5) and [Ni3(dia)5(5-sip)2]·6DMF·14H2O (6). Structure analyses involving single-crystal X-ray diffraction (SCXRD), powder X-ray diffraction (PXRD) and Fourier-transform infrared spectroscopy (FT-IR) were conducted along with studies determining the thermal stabilities and optical properties of the compounds. The results indicate that the developed fast and green syntheses can produce pure CP and MOF phases that have various thermally stable and visible light absorbing structures which may find applications in photocatalysis.en
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.relation.ispartofseriesCrystEngComm
dc.rightsCC BY 3.0
dc.titleAqueous syntheses of anthracene-based mixed-ligand coordination polymers and their structural and optical properties
dc.typearticle
dc.identifier.urnURN:NBN:fi:jyu-202406194785
dc.contributor.laitosKemian laitosfi
dc.contributor.laitosDepartment of Chemistryen
dc.type.urihttp://purl.org/eprint/type/JournalArticle
dc.type.coarhttp://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatuspeerReviewed
dc.relation.issn1466-8033
dc.relation.volumeEarly online
dc.type.versionpublishedVersion
dc.rights.copyright© 2024 Royal Society of Chemistry
dc.rights.accesslevelopenAccessfi
dc.subject.ysopolymeerit
dc.subject.ysokiteet
dc.subject.ysokemiallinen synteesi
dc.subject.ysooptiset ominaisuudet
dc.subject.ysoorganometalliyhdisteet
dc.format.contentfulltext
jyx.subject.urihttp://www.yso.fi/onto/yso/p926
jyx.subject.urihttp://www.yso.fi/onto/yso/p15440
jyx.subject.urihttp://www.yso.fi/onto/yso/p8468
jyx.subject.urihttp://www.yso.fi/onto/yso/p25870
jyx.subject.urihttp://www.yso.fi/onto/yso/p28123
dc.rights.urlhttps://creativecommons.org/licenses/by/3.0/
dc.relation.doi10.1039/d4ce00399c
jyx.fundinginformationThe authors acknowledge the financial support from the Magnus Ehrnrooth Foundation and the University of Jyväskylä.
dc.type.okmA1


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