Synthesis of Benzo[e][1,4,3]oxathiazin-3-one 1-Oxides from NH-S-(2-Hydroxyaryl)sulfoximines

Periasamy, Kiruthika; van Bonn, Pit; Tschekorsky Orloff, Runa; Völcker, Nils; Lu, Qiulan; Rissanen, Kari; Bolm, Carsten

doi:10.1021/acs.joc.4c00712

dc.contributor.author	Periasamy, Kiruthika
dc.contributor.author	van Bonn, Pit
dc.contributor.author	Tschekorsky Orloff, Runa
dc.contributor.author	Völcker, Nils
dc.contributor.author	Lu, Qiulan
dc.contributor.author	Rissanen, Kari
dc.contributor.author	Bolm, Carsten
dc.date.accessioned	2024-06-07T12:13:25Z
dc.date.available	2024-06-07T12:13:25Z
dc.date.issued	2024
dc.identifier.citation	Periasamy, K., van Bonn, P., Tschekorsky Orloff, R., Völcker, N., Lu, Q., Rissanen, K., & Bolm, C. (2024). Synthesis of Benzo[e][1,4,3]oxathiazin-3-one 1-Oxides from NH-S-(2-Hydroxyaryl)sulfoximines. <i>Journal of Organic Chemistry</i>, <i>Early online</i>. <a href="https://doi.org/10.1021/acs.joc.4c00712" target="_blank">https://doi.org/10.1021/acs.joc.4c00712</a>
dc.identifier.other	CONVID_213694923
dc.identifier.uri	https://jyx.jyu.fi/handle/123456789/95675
dc.description.abstract	Cyclizations of NH-S-(2-hydroxyaryl)sulfoximines with 1,1′-carbonyldiimidazol (CDI) give unprecedented benzo[e][1,4,3]oxathiazin-3-one 1-oxides in good yields. The standard synthetic protocol involves the use of DCE at an increased temperature for 16 h. Under mechanochemical conditions, a representative product was obtained without a solvent at ambient temperature in only 60 min. X-ray single-crystal structure analysis confirmed the molecular scaffold representing a three-dimensional heterocycle.	en
dc.format.mimetype	application/pdf
dc.language.iso	eng
dc.publisher	American Chemical Society (ACS)
dc.relation.ispartofseries	Journal of Organic Chemistry
dc.rights	In Copyright
dc.subject.other	chemical structure
dc.subject.other	heterocyclic compounds
dc.subject.other	nitrogen
dc.subject.other	solvents
dc.subject.other	substituents
dc.title	Synthesis of Benzo[e][1,4,3]oxathiazin-3-one 1-Oxides from NH-S-(2-Hydroxyaryl)sulfoximines
dc.type	research article
dc.identifier.urn	URN:NBN:fi:jyu-202406074436
dc.contributor.laitos	Kemian laitos	fi
dc.contributor.laitos	Department of Chemistry	en
dc.type.uri	http://purl.org/eprint/type/JournalArticle
dc.type.coar	http://purl.org/coar/resource_type/c_2df8fbb1
dc.description.reviewstatus	peerReviewed
dc.relation.issn	0022-3263
dc.relation.volume	Early online
dc.type.version	acceptedVersion
dc.rights.copyright	© 2024 American Chemical Society
dc.rights.accesslevel	embargoedAccess	fi
dc.type.publication	article
dc.subject.yso	oksidit
dc.subject.yso	heterosykliset yhdisteet
dc.subject.yso	kemiallinen synteesi
dc.format.content	fulltext
jyx.subject.uri	http://www.yso.fi/onto/yso/p2803
jyx.subject.uri	http://www.yso.fi/onto/yso/p38837
jyx.subject.uri	http://www.yso.fi/onto/yso/p8468
dc.rights.url	http://rightsstatements.org/page/InC/1.0/?language=en
dc.relation.doi	10.1021/acs.joc.4c00712
dc.type.okm	A1

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