Synthesis of Benzo[e][1,4,3]oxathiazin-3-one 1-Oxides from NH-S-(2-Hydroxyaryl)sulfoximines
| dc.contributor.author | Periasamy, Kiruthika | |
| dc.contributor.author | van Bonn, Pit | |
| dc.contributor.author | Tschekorsky Orloff, Runa | |
| dc.contributor.author | Völcker, Nils | |
| dc.contributor.author | Lu, Qiulan | |
| dc.contributor.author | Rissanen, Kari | |
| dc.contributor.author | Bolm, Carsten | |
| dc.date.accessioned | 2024-06-07T12:13:25Z | |
| dc.date.available | 2024-06-07T12:13:25Z | |
| dc.date.issued | 2024 | |
| dc.identifier.citation | Periasamy, K., van Bonn, P., Tschekorsky Orloff, R., Völcker, N., Lu, Q., Rissanen, K., & Bolm, C. (2024). Synthesis of Benzo[e][1,4,3]oxathiazin-3-one 1-Oxides from NH-S-(2-Hydroxyaryl)sulfoximines. <i>Journal of Organic Chemistry</i>, <i>Early online</i>. <a href="https://doi.org/10.1021/acs.joc.4c00712" target="_blank">https://doi.org/10.1021/acs.joc.4c00712</a> | |
| dc.identifier.other | CONVID_213694923 | |
| dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/95675 | |
| dc.description.abstract | Cyclizations of NH-S-(2-hydroxyaryl)sulfoximines with 1,1′-carbonyldiimidazol (CDI) give unprecedented benzo[e][1,4,3]oxathiazin-3-one 1-oxides in good yields. The standard synthetic protocol involves the use of DCE at an increased temperature for 16 h. Under mechanochemical conditions, a representative product was obtained without a solvent at ambient temperature in only 60 min. X-ray single-crystal structure analysis confirmed the molecular scaffold representing a three-dimensional heterocycle. | en |
| dc.format.mimetype | application/pdf | |
| dc.language.iso | eng | |
| dc.publisher | American Chemical Society (ACS) | |
| dc.relation.ispartofseries | Journal of Organic Chemistry | |
| dc.rights | In Copyright | |
| dc.subject.other | chemical structure | |
| dc.subject.other | heterocyclic compounds | |
| dc.subject.other | nitrogen | |
| dc.subject.other | solvents | |
| dc.subject.other | substituents | |
| dc.title | Synthesis of Benzo[e][1,4,3]oxathiazin-3-one 1-Oxides from NH-S-(2-Hydroxyaryl)sulfoximines | |
| dc.type | research article | |
| dc.identifier.urn | URN:NBN:fi:jyu-202406074436 | |
| dc.contributor.laitos | Kemian laitos | fi |
| dc.contributor.laitos | Department of Chemistry | en |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
| dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
| dc.description.reviewstatus | peerReviewed | |
| dc.relation.issn | 0022-3263 | |
| dc.relation.volume | Early online | |
| dc.type.version | acceptedVersion | |
| dc.rights.copyright | © 2024 American Chemical Society | |
| dc.rights.accesslevel | embargoedAccess | fi |
| dc.type.publication | article | |
| dc.subject.yso | oksidit | |
| dc.subject.yso | heterosykliset yhdisteet | |
| dc.subject.yso | kemiallinen synteesi | |
| dc.format.content | fulltext | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p2803 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p38837 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p8468 | |
| dc.rights.url | http://rightsstatements.org/page/InC/1.0/?language=en | |
| dc.relation.doi | 10.1021/acs.joc.4c00712 | |
| dc.type.okm | A1 |
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