Synthesis, characterisation and reactivity of a zinc triazenide for potential use in vapour deposition
| dc.contributor.author | Samii, Rouzbeh | |
| dc.contributor.author | Barkas, Essi | |
| dc.contributor.author | Zanders, David | |
| dc.contributor.author | Fransson, Anton | |
| dc.contributor.author | Lahtinen, Manu | |
| dc.contributor.author | Kessler, Vadim | |
| dc.contributor.author | Tuononen, Heikki M. | |
| dc.contributor.author | Moilanen, Jani O. | |
| dc.contributor.author | O'Brien, Nathan J. | |
| dc.date.accessioned | 2024-03-15T13:36:19Z | |
| dc.date.available | 2024-03-15T13:36:19Z | |
| dc.date.issued | 2024 | |
| dc.identifier.citation | Samii, R., Barkas, E., Zanders, D., Fransson, A., Lahtinen, M., Kessler, V., Tuononen, H. M., Moilanen, J. O., & O'Brien, N. J. (2024). Synthesis, characterisation and reactivity of a zinc triazenide for potential use in vapour deposition. <i>Dalton Transactions</i>, <i>53</i>(13), 5911-5916. <a href="https://doi.org/10.1039/D4DT00084F" target="_blank">https://doi.org/10.1039/D4DT00084F</a> | |
| dc.identifier.other | CONVID_207584626 | |
| dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/93947 | |
| dc.description.abstract | In this study, we synthesised and characterised a new zinc(II) triazenide for potential use in vapour deposition of zinc sulphide thin films. The compound is volatile and quantitatively sublimes at 80 °C under vacuum (0.5 mbar). Thermogravimetric analysis showed a one-step volatilisation with an onset temperature at ∼125 °C and 5% residual mass. The compound also reacted with 2 or 4 molar equivalents of triphenylsilanethiol to give dimeric and monomeric zinc thiolates, respectively. The high volatility, thermal stability, and reactivity with sterically hindered thiols makes this compound a potential candidate for use in vapour deposition of zinc containing thin films. | en |
| dc.format.mimetype | application/pdf | |
| dc.language.iso | eng | |
| dc.publisher | Royal Society of Chemistry | |
| dc.relation.ispartofseries | Dalton Transactions | |
| dc.rights | CC BY 3.0 | |
| dc.title | Synthesis, characterisation and reactivity of a zinc triazenide for potential use in vapour deposition | |
| dc.type | article | |
| dc.identifier.urn | URN:NBN:fi:jyu-202403152462 | |
| dc.contributor.laitos | Kemian laitos | fi |
| dc.contributor.laitos | Department of Chemistry | en |
| dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
| dc.contributor.oppiaine | Nanoscience Center | fi |
| dc.contributor.oppiaine | Epäorgaaninen kemia | fi |
| dc.contributor.oppiaine | Resurssiviisausyhteisö | fi |
| dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
| dc.contributor.oppiaine | Nanoscience Center | en |
| dc.contributor.oppiaine | Inorganic Chemistry | en |
| dc.contributor.oppiaine | School of Resource Wisdom | en |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
| dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
| dc.description.reviewstatus | peerReviewed | |
| dc.format.pagerange | 5911-5916 | |
| dc.relation.issn | 1477-9226 | |
| dc.relation.numberinseries | 13 | |
| dc.relation.volume | 53 | |
| dc.type.version | publishedVersion | |
| dc.rights.copyright | © 2024 The Royal Society of Chemistry | |
| dc.rights.accesslevel | openAccess | fi |
| dc.relation.grantnumber | 315829 | |
| dc.relation.grantnumber | 338733 | |
| dc.subject.yso | ohutkalvot | |
| dc.subject.yso | kemiallinen kaasufaasipinnoitus | |
| dc.subject.yso | sinkki (metallit) | |
| dc.format.content | fulltext | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p16644 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p39016 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p15062 | |
| dc.rights.url | https://creativecommons.org/licenses/by/3.0/ | |
| dc.relation.doi | 10.1039/D4DT00084F | |
| dc.relation.funder | Research Council of Finland | en |
| dc.relation.funder | Research Council of Finland | en |
| dc.relation.funder | Suomen Akatemia | fi |
| dc.relation.funder | Suomen Akatemia | fi |
| jyx.fundingprogram | Academy Research Fellow, AoF | en |
| jyx.fundingprogram | Academy Project, AoF | en |
| jyx.fundingprogram | Akatemiatutkija, SA | fi |
| jyx.fundingprogram | Akatemiahanke, SA | fi |
| jyx.fundinginformation | The project was funded by the Swedish Foundation for Strategic Research through the project “Time-resolved low temperature CVD for III-nitrides” (SSF-RMA 15-0018) and by the Knut and Alice Wallenberg foundation through the project “Bridging the THz gap” (No. KAW 2013.0049). E. B. and J. O. M. acknowledge the Research Council of Finland (projects 315829 and 338733) for financial support. | |
| dc.type.okm | A1 |
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