Bifunctional coordination polymers as efficient catalysts for carbon dioxide conversion
| dc.contributor.author | Arunachalam, Rajendran | |
| dc.contributor.author | Chinnaraja, Eswaran | |
| dc.contributor.author | Valkonen, Arto | |
| dc.contributor.author | Rissanen, Kari | |
| dc.contributor.author | Subramanian, Palani S. | |
| dc.date.accessioned | 2024-03-04T08:09:05Z | |
| dc.date.available | 2024-03-04T08:09:05Z | |
| dc.date.issued | 2019 | |
| dc.identifier.citation | Arunachalam, R., Chinnaraja, E., Valkonen, A., Rissanen, K., & Subramanian, P. S. (2019). Bifunctional coordination polymers as efficient catalysts for carbon dioxide conversion. <i>Applied Organometallic Chemistry</i>, <i>33</i>(11), Article e5202. <a href="https://doi.org/10.1002/aoc.5202" target="_blank">https://doi.org/10.1002/aoc.5202</a> | |
| dc.identifier.other | CONVID_32670915 | |
| dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/93782 | |
| dc.description.abstract | The multidentate ligand H2L upon complexation with Zn (II) and Cd (II) provide a one‐dimensional polymeric networks. These coordination polymers (CPs) CP‐1 and CP‐2 containing Zn (II) and Cd (II) metals respectively are well characterized. The single crystal structural analysis confirms the formation of one‐dimensional coordination polymer with zigzag fashion in CP‐1 and ladder chain CP‐2. Both the CPs are applied as catalysts to synthesize various cyclic carbonates from epoxides and carbon dioxide. The catalysts are giving better conversion under solvent‐free and additive‐free condition using 10 bar CO2 and 100 °C as optimized pressure and temperature. The detailed kinetic experiments suggesting the first order kinetics, the energy of activation (Ea) is calculated for this catalytic conversion. | en |
| dc.format.mimetype | application/pdf | |
| dc.language.iso | eng | |
| dc.publisher | John Wiley & Sons | |
| dc.relation.ispartofseries | Applied Organometallic Chemistry | |
| dc.rights | In Copyright | |
| dc.subject.other | activation energy | |
| dc.subject.other | CO2utilization | |
| dc.subject.other | coordination polymers | |
| dc.subject.other | cyclic carbonates | |
| dc.subject.other | reaction kinetics | |
| dc.title | Bifunctional coordination polymers as efficient catalysts for carbon dioxide conversion | |
| dc.type | article | |
| dc.identifier.urn | URN:NBN:fi:jyu-202403042249 | |
| dc.contributor.laitos | Kemian laitos | fi |
| dc.contributor.laitos | Department of Chemistry | en |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
| dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
| dc.description.reviewstatus | peerReviewed | |
| dc.relation.issn | 0268-2605 | |
| dc.relation.numberinseries | 11 | |
| dc.relation.volume | 33 | |
| dc.type.version | acceptedVersion | |
| dc.rights.copyright | © 2019 John Wiley & Sons, Ltd. | |
| dc.rights.accesslevel | openAccess | fi |
| dc.relation.grantnumber | 314343 | |
| dc.subject.yso | kemialliset reaktiot | |
| dc.subject.yso | polymeerit | |
| dc.subject.yso | hiilidioksidi | |
| dc.format.content | fulltext | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p3658 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p926 | |
| jyx.subject.uri | http://www.yso.fi/onto/yso/p4728 | |
| dc.rights.url | http://rightsstatements.org/page/InC/1.0/?language=en | |
| dc.relation.doi | 10.1002/aoc.5202 | |
| dc.relation.funder | Suomen Akatemia | fi |
| dc.relation.funder | Research Council of Finland | en |
| jyx.fundingprogram | Akatemiatutkijan tutkimuskulut, SA | fi |
| jyx.fundingprogram | Research costs of Academy Research Fellow, AoF | en |
| jyx.fundinginformation | CSMCRI communication number 006/2019. R. A and E. C acknowledge CSIR for SRF and Indus Magic project no CSC‐0123 for financial assistance. Dr. S. Kannan is greatly acknowledged for the reactor facilities to perform this work. Dr. E. Suresh is acknowledged for his assistance of single crystal description. Dr. P. S acknowledges the CSIR for Indus Magic Project No. CSC‐0123 and DST‐SERB New Delhi (project No SR/S1/IC‐23/2011) for financial support. A. V. also kindly acknowledges the Academy of Finland (grant no. 314343) for financial support. We are thankful to ADCIF for the instrument support. | |
| dc.type.okm | A1 |
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