dc.contributor.author | Altowyan, Mezna Saleh | |
dc.contributor.author | Fathalla, Eman M. | |
dc.contributor.author | Albering, Jörg H. | |
dc.contributor.author | Abu-Youssef, Morsy A. M. | |
dc.contributor.author | Kassem, Taher S. | |
dc.contributor.author | Barakat, Assem | |
dc.contributor.author | Haukka, Matti | |
dc.contributor.author | Badr, Ahmed M. A. | |
dc.contributor.author | Soliman, Saied M. | |
dc.date.accessioned | 2023-11-02T12:21:37Z | |
dc.date.available | 2023-11-02T12:21:37Z | |
dc.date.issued | 2023 | |
dc.identifier.citation | Altowyan, M. S., Fathalla, E. M., Albering, J. H., Abu-Youssef, M. A. M., Kassem, T. S., Barakat, A., Haukka, M., Badr, A. M. A., & Soliman, S. M. (2023). Synthesis, X-ray Structures and Hirshfeld Analysis of Two Novel Thiocyanate-Bridged Ag(I) Coordination Polymers. <i>Inorganics</i>, <i>11</i>(10), Article 417. <a href="https://doi.org/10.3390/inorganics11100417" target="_blank">https://doi.org/10.3390/inorganics11100417</a> | |
dc.identifier.other | CONVID_194280067 | |
dc.identifier.uri | https://jyx.jyu.fi/handle/123456789/91375 | |
dc.description.abstract | Two novel silver(I) coordination polymers, [Ag(4BP)(SCN)]n (1) and {(4BPH)+[Ag(SCN)2]−}n (2) (4BP = 4-benzoyl pyridine), have been synthesized. The two complexes were prepared using almost the same reagents, which were AgNO3, 4BP and NH4SCN. The only difference was the presence of 1:1 (v/v) HNO3 in the synthesis of 2. In the two complexes, the Ag(I) has distorted tetrahedral coordination geometry. The structure of both complexes and the involvement of the thiocyanate anion as a linker between the Ag(I) centers were confirmed using single-crystal X-ray diffraction. 4BP participated as a monodentate ligand in the coordination sphere of complex 1, while in 2 it is found protonated (4BP-H)+ and acts as a counter ion, which balances the charge of the anionic [Ag(SCN)2]− moiety. The thiocyanate anion shows different coordination modes in the two complexes. In complex 1, the thiocyanate anion exhibits a µ1,1,3 bridging mode, which binds three Ag(I) ions to build a boat-like ten-membered ring structure leading to a two-dimensional coordination polymer. In 2, there are mixed µ1,1 and µ1,3 bridging thiocyanate groups, which form the one-dimensional polymeric chain running in the a-direction. Several interactions affected the stability of the crystal structure of the two complexes. These interactions were examined using Hirshfeld surface analysis. The coordination interactions (Ag-S and Ag-N) have a great impact on the stability of the polymeric structure of the two complexes. Additionally, the hydrogen-bonding interactions are crucial in the assembly of these coordination polymers. The O…H (10.7%) and C…H (34.2%) contacts in 1 as well as the N···H (15.3%) and S···H (14.9%) contacts in 2 are the most significant. Moreover, the argentophilic interaction (Ag…Ag = 3.378 Å) and π- π stacking play an important role in the assembly of complex 2. | en |
dc.format.mimetype | application/pdf | |
dc.language.iso | eng | |
dc.publisher | MDPI | |
dc.relation.ispartofseries | Inorganics | |
dc.rights | CC BY 4.0 | |
dc.subject.other | AgSCN coordination polymer | |
dc.subject.other | 4-benzoyl pyridine | |
dc.subject.other | X-ray diffraction | |
dc.subject.other | supramolecular | |
dc.subject.other | Hirshfeld | |
dc.title | Synthesis, X-ray Structures and Hirshfeld Analysis of Two Novel Thiocyanate-Bridged Ag(I) Coordination Polymers | |
dc.type | article | |
dc.identifier.urn | URN:NBN:fi:jyu-202311027396 | |
dc.contributor.laitos | Kemian laitos | fi |
dc.contributor.laitos | Department of Chemistry | en |
dc.contributor.oppiaine | Epäorgaaninen ja analyyttinen kemia | fi |
dc.contributor.oppiaine | Epäorgaaninen kemia | fi |
dc.contributor.oppiaine | Inorganic and Analytical Chemistry | en |
dc.contributor.oppiaine | Inorganic Chemistry | en |
dc.type.uri | http://purl.org/eprint/type/JournalArticle | |
dc.type.coar | http://purl.org/coar/resource_type/c_2df8fbb1 | |
dc.description.reviewstatus | peerReviewed | |
dc.relation.issn | 2304-6740 | |
dc.relation.numberinseries | 10 | |
dc.relation.volume | 11 | |
dc.type.version | publishedVersion | |
dc.rights.copyright | © 2023 the Authors | |
dc.rights.accesslevel | openAccess | fi |
dc.subject.yso | polymeerit | |
dc.subject.yso | supramolekulaarinen kemia | |
dc.subject.yso | hopea | |
dc.subject.yso | diffraktio | |
dc.subject.yso | röntgensäteily | |
dc.format.content | fulltext | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p926 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p37759 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p7409 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p39312 | |
jyx.subject.uri | http://www.yso.fi/onto/yso/p1297 | |
dc.rights.url | https://creativecommons.org/licenses/by/4.0/ | |
dc.relation.doi | 10.3390/inorganics11100417 | |
jyx.fundinginformation | Princess Nourah bint Abdulrahman University Researchers Supporting Project number (PNURSP2023R86), Princess Nourah bint Abdulrahman University, Riyadh, Saudi Arabia. | |
dc.type.okm | A1 | |